HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX

TANG Liming; HUANG Meiyu; JIANG Yingyan

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HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX

Papers | Updated：2021-06-21

- HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX
- Vol. 13, Issue 4, Pages: 331-337(1995)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： O643.3
- Published：20 December 1995
- Accepted：
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[1]唐黎明,黄美玉,江英彦.HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX[J].Chinese Journal of Polymer Science,1995,{4}(04):331-337.

TANG Liming, HUANG Meiyu, JIANG Yingyan. HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX[J]. 1995, 13(4): 331-337.
[1]唐黎明,黄美玉,江英彦.HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX[J].Chinese Journal of Polymer Science,1995,{4}(04):331-337. DOI：

TANG Liming, HUANG Meiyu, JIANG Yingyan. HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX[J]. 1995, 13(4): 331-337. DOI：

摘要

正

A silica-supported poly-γ- aminopropylsiloxane-rhodium-cobalt bimetallic complex（abbreviated as SiO

-NH

-Rh-Co）has been prepared and used as catalyst for hydroformylationof methyl methacrylate. The results showed that the catalyst could catalyze the reaction in95.6% conversion with 92.8% selectivity for the normal aldehyde

methyl β-formylisobu-tyrate. Such catalyst also showed high stability during the reaction and could be used repeat-edly.

Abstract

A silica-supported poly-γ- aminopropylsiloxane-rhodium-cobalt bimetallic complex（abbreviated as SiO

-NH

methyl β-formylisobu-tyrate. Such catalyst also showed high stability during the reaction and could be used repeat-edly.

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