<正> Semi-rigid liquid crystal polymer is a class of liquid crystal polymers different from long rigidrod liquid crystal polymer to which the well-known Onsager and Flory theories are applied. Inthis paper
three statistical models for the semi-rigid nematic polymer were addressed. They arethe elastically jointed rod model
worm-like chain model
and non--homogeneous chain model.The nematic-isotropic transition temperature was examined. The pseudo-second transition tem-perature is expressed analytically. Comparisons with the experiments were made and the agree-ments were found.
Abstract
Semi-rigid liquid crystal polymer is a class of liquid crystal polymers different from long rigidrod liquid crystal polymer to which the well-known Onsager and Flory theories are applied. Inthis paper
three statistical models for the semi-rigid nematic polymer were addressed. They arethe elastically jointed rod model
worm-like chain model
and non--homogeneous chain model.The nematic-isotropic transition temperature was examined. The pseudo-second transition tem-perature is expressed analytically. Comparisons with the experiments were made and the agree-ments were found.
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