POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER

WANG Mingtai; ZONG Huijuan

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POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER

Papers | Updated：2021-06-21

- POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER
- Vol. 13, Issue 1, Pages: 84-90(1995)
- Affiliations：
  
  1.   Department of Materials Science & Engineering
  2.   University of Science and Technology of China
  3.   Hefei
  4.   Anhui 230026
- Author bio：
- Funds：
- DOI：
  CLC： O631.3
- Published：20 March 1995
- Accepted：
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[1]王命泰,宗惠娟.POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER[J].Chinese Journal of Polymer Science,1995,{4}(01):84-90.

WANG Mingtai, ZONG Huijuan. POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER[J]. 1995, 13(1): 84-90.
[1]王命泰,宗惠娟.POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER[J].Chinese Journal of Polymer Science,1995,{4}(01):84-90. DOI：

WANG Mingtai, ZONG Huijuan. POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER[J]. 1995, 13(1): 84-90. DOI：

摘要

<正> Polymeric Grignard Reagent （PGR） based on the chloromethylated poly（ST-co-DVB） resinhas been prepared by means of anthracene-magnesium complex in THF （Anth-Mg-THF）

andpolymer matrix with long polymethylene spacer was synthesized via the coupling reaction betweenPGR and α

ω-dibromoalkanes. Based on the studies of factors affecting the coupling

such ascatalyst

reaction time

the length of spacer etc.

this paper offers the optimal reaction conditionsand three typical experiment procedures. The mechanism for the formation and coupling reactionof PGR are also discussed.

Abstract

Polymeric Grignard Reagent （PGR） based on the chloromethylated poly（ST-co-DVB） resinhas been prepared by means of anthracene-magnesium complex in THF （Anth-Mg-THF）

andpolymer matrix with long polymethylene spacer was synthesized via the coupling reaction betweenPGR and α

ω-dibromoalkanes. Based on the studies of factors affecting the coupling

such ascatalyst

reaction time

the length of spacer etc.

this paper offers the optimal reaction conditionsand three typical experiment procedures. The mechanism for the formation and coupling reactionof PGR are also discussed.

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