STEREOREGULARITY OF POLY (METHYL METHACRYLATE) OBTAINED WITH CHIRAL ANIONIC COMPLEX INITIATOR*

CHEN Chuanfu; REN Changyu; XI Fu

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STEREOREGULARITY OF POLY (METHYL METHACRYLATE) OBTAINED WITH CHIRAL ANIONIC COMPLEX INITIATOR*

Papers | Updated：2021-06-21

- STEREOREGULARITY OF POLY (METHYL METHACRYLATE) OBTAINED WITH CHIRAL ANIONIC COMPLEX INITIATOR*
- Vol. 13, Issue 1, Pages: 91-96(1995)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： O631.5
- Published：20 March 1995
- Accepted：
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[1]陈传福,任长玉,习复.STEREOREGULARITY OF POLY (METHYL METHACRYLATE) OBTAINED WITH CHIRAL ANIONIC COMPLEX INITIATOR[J].Chinese Journal of Polymer Science,1995,{4}(01):91-96.

CHEN Chuanfu, REN Changyu, XI Fu. STEREOREGULARITY OF POLY (METHYL METHACRYLATE) OBTAINED WITH CHIRAL ANIONIC COMPLEX INITIATOR*[J]. 1995, 13(1): 91-96.
[1]陈传福,任长玉,习复.STEREOREGULARITY OF POLY (METHYL METHACRYLATE) OBTAINED WITH CHIRAL ANIONIC COMPLEX INITIATOR[J].Chinese Journal of Polymer Science,1995,{4}(01):91-96. DOI：

CHEN Chuanfu, REN Changyu, XI Fu. STEREOREGULARITY OF POLY (METHYL METHACRYLATE) OBTAINED WITH CHIRAL ANIONIC COMPLEX INITIATOR*[J]. 1995, 13(1): 91-96. DOI：

摘要

<正> The stereoregular polymerization of methyl methacrylate （MMA） have been investigatedwith chiral anionic complex initiator[FILi-（-）SP]in toluene

THF and toluene/THF [1/1（v/v）]. The tacticities of PMMAs obtained in the three solvents have been found to be mainly asyndiotactic triads（s-PMMA）with content of 72.3

67.7 and 71.4%

respectively.

Abstract

The stereoregular polymerization of methyl methacrylate （MMA） have been investigatedwith chiral anionic complex initiator[FILi-（-）SP]in toluene

THF and toluene/THF [1/1（v/v）]. The tacticities of PMMAs obtained in the three solvents have been found to be mainly asyndiotactic triads（s-PMMA）with content of 72.3

67.7 and 71.4%

respectively.

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