SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE
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SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE
Vol. 13, Issue 3, Pages: 264-272(1995)
Affiliations:
1. Changchun Institute of Applied Chemistry
2. Academia Sinica
3. Changchun 130022
Author bio:
Funds:
DOI:
CLC:TQ317
Published:20 September 1995
Accepted:
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[1]丁黎明,林云青,周子南,倪建龙,陈东霖.SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE[J].Chinese Journal of Polymer Science,1995,{4}(03):264-272.
DING Liming, LIN Yunqing, ZHOU Zinan, et al. SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE[J]. 1995, 13(3): 264-272.
[1]丁黎明,林云青,周子南,倪建龙,陈东霖.SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE[J].Chinese Journal of Polymer Science,1995,{4}(03):264-272.DOI:
DING Liming, LIN Yunqing, ZHOU Zinan, et al. SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE[J]. 1995, 13(3): 264-272.DOI:
SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE
A new comblike polymer host for polymer electrolyte was synthesized by reactingmonomethyl ether of poly (ethylene glycol) with poly (vinyl methyl ether alt-maleic anhydride)and endcapping the residual carboxylic acid with methanol. Butanone was selected as a solventfor the esterification in order to obtain a completely soluble product. The synthesis processwas traced through by IR. Compared with the model compounds
the presumed structure ofthis comblike polymer has been proved to be valid by
13
C NMR. The comb polymer is a whiterubbery solid. It can be dissolved in butanone and THF
and manifests good film formingability.
Abstract
A new comblike polymer host for polymer electrolyte was synthesized by reactingmonomethyl ether of poly (ethylene glycol) with poly (vinyl methyl ether alt-maleic anhydride)and endcapping the residual carboxylic acid with methanol. Butanone was selected as a solventfor the esterification in order to obtain a completely soluble product. The synthesis processwas traced through by IR. Compared with the model compounds
the presumed structure ofthis comblike polymer has been proved to be valid by
13
C NMR. The comb polymer is a whiterubbery solid. It can be dissolved in butanone and THF
and manifests good film formingability.
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