SYNTHESIS OF MESOGENIC POLYESTERS WITH 2-DICHLOROMETHYLHYDROQUINONE MOIETIES*
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SYNTHESIS OF MESOGENIC POLYESTERS WITH 2-DICHLOROMETHYLHYDROQUINONE MOIETIES*
Vol. 13, Issue 3, Pages: 285-288(1995)
Affiliations:
1. Department of Chemistry
2. Peking University
3. Beijing 100871
Author bio:
Funds:
DOI:
CLC:TQ317
Published:20 September 1995
Accepted:
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[1]周其风,郭爱兰.SYNTHESIS OF MESOGENIC POLYESTERS WITH 2-DICHLOROMETHYLHYDROQUINONE MOIETIES[J].Chinese Journal of Polymer Science,1995,{4}(03):285-288.
ZHOU Qifeng, Guo Ailan. SYNTHESIS OF MESOGENIC POLYESTERS WITH 2-DICHLOROMETHYLHYDROQUINONE MOIETIES*[J]. 1995, 13(3): 285-288.
[1]周其风,郭爱兰.SYNTHESIS OF MESOGENIC POLYESTERS WITH 2-DICHLOROMETHYLHYDROQUINONE MOIETIES[J].Chinese Journal of Polymer Science,1995,{4}(03):285-288.DOI:
ZHOU Qifeng, Guo Ailan. SYNTHESIS OF MESOGENIC POLYESTERS WITH 2-DICHLOROMETHYLHYDROQUINONE MOIETIES*[J]. 1995, 13(3): 285-288.DOI:
SYNTHESIS OF MESOGENIC POLYESTERS WITH 2-DICHLOROMETHYLHYDROQUINONE MOIETIES*
<正> A series of novel mesogenic polyesters with 2-dich1oromethylhydroquinone moieties weresynthesized by polycondensation of the novel diacyl chloride monomer 2-dichloromethyl-1
4-bis (4’-chloroformylbenzoyl) oxybenzene-(I) with α
ω-polymethylenediols including ethyleneglycol
1
4-butanediol
1
6-hexanediol and 1
10-decanediol. The diacyl chloride monomerwas synthesized by simultaneous transformations of both the carboxy and formaldehydegroups of 2-formyl-1
4-bis (4’-carboxybenzoyl) oxybenzene into acyl chloride anddichloromethyl groups respectively. The syntheses of the monomer (I) and the polymers werereported.
Abstract
A series of novel mesogenic polyesters with 2-dich1oromethylhydroquinone moieties weresynthesized by polycondensation of the novel diacyl chloride monomer 2-dichloromethyl-1
4-bis (4’-chloroformylbenzoyl) oxybenzene-(I) with α
ω-polymethylenediols including ethyleneglycol
1
4-butanediol
1
6-hexanediol and 1
10-decanediol. The diacyl chloride monomerwas synthesized by simultaneous transformations of both the carboxy and formaldehydegroups of 2-formyl-1
4-bis (4’-carboxybenzoyl) oxybenzene into acyl chloride anddichloromethyl groups respectively. The syntheses of the monomer (I) and the polymers werereported.
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