CROWN FUNCTIONALIZED LINEAR POLYSILOXANE PLATINUM COMPLEX AS HYDROSILYLATION CATALYST*

CHEN Yuanyin; LU Xueran; GONG Shuling; ZHANG Baolian

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CROWN FUNCTIONALIZED LINEAR POLYSILOXANE PLATINUM COMPLEX AS HYDROSILYLATION CATALYST*

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- CROWN FUNCTIONALIZED LINEAR POLYSILOXANE PLATINUM COMPLEX AS HYDROSILYLATION CATALYST*
- Vol. 12, Issue 4, Pages: 352-357(1994)
- Affiliations：
  
  1.   Department of Chemistry
  2.   Wuhan University
  3.   Wuhan 430072
- Author bio：
- Funds：
- DOI：
  CLC： O634.41
- Published：20 December 1994
- Accepted：
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[1]陈远荫,卢雪然,龚淑玲,张宝莲.CROWN FUNCTIONALIZED LINEAR POLYSILOXANE PLATINUM COMPLEX AS HYDROSILYLATION CATALYST[J].Chinese Journal of Polymer Science,1994,{4}(04):352-357.

CHEN Yuanyin, LU Xueran, GONG Shuling, et al. CROWN FUNCTIONALIZED LINEAR POLYSILOXANE PLATINUM COMPLEX AS HYDROSILYLATION CATALYST*[J]. 1994, 12(4): 352-357.
[1]陈远荫,卢雪然,龚淑玲,张宝莲.CROWN FUNCTIONALIZED LINEAR POLYSILOXANE PLATINUM COMPLEX AS HYDROSILYLATION CATALYST[J].Chinese Journal of Polymer Science,1994,{4}(04):352-357. DOI：

CHEN Yuanyin, LU Xueran, GONG Shuling, et al. CROWN FUNCTIONALIZED LINEAR POLYSILOXANE PLATINUM COMPLEX AS HYDROSILYLATION CATALYST*[J]. 1994, 12(4): 352-357. DOI：

摘要

<正> A modified method of preparing crown functionalized linear polysiloxane has been described.4’-allylbenzo-15-crown-5 was subjected to hydrosilylation with methyldichlorosilane

followed bypolycondensation with silanol-terminated polydimethylsiloxane to give the title crownfunctionalized linear polysiloxane. It was found that the polysiloxane could be coordinated withplatinum salt to form platinum complex

which could catalyze the hydrosilylation of olefins withtriethoxysilane efficiently.

Abstract

A modified method of preparing crown functionalized linear polysiloxane has been described.4’-allylbenzo-15-crown-5 was subjected to hydrosilylation with methyldichlorosilane

which could catalyze the hydrosilylation of olefins withtriethoxysilane efficiently.

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