STUDY ON THERMAL DECOMPOSITION KINETICS OF URUSHIOL METAL CHELATE POLYMERS*
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STUDY ON THERMAL DECOMPOSITION KINETICS OF URUSHIOL METAL CHELATE POLYMERS*
Vol. 12, Issue 4, Pages: 358-365(1994)
Affiliations:
1. Fujian Normal University
2. Fuzhou 350007
Author bio:
Funds:
DOI:
CLC:O631.3
Published:20 December 1994
Accepted:
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[1]胡炳环,陈日耀,林金火,陈文定.STUDY ON THERMAL DECOMPOSITION KINETICS OF URUSHIOL METAL CHELATE POLYMERS[J].Chinese Journal of Polymer Science,1994,{4}(04):358-365.
HU Binghuan, CHEN Riyao, LIN Jinhuo. STUDY ON THERMAL DECOMPOSITION KINETICS OF URUSHIOL METAL CHELATE POLYMERS*[J]. 1994, 12(4): 358-365.
[1]胡炳环,陈日耀,林金火,陈文定.STUDY ON THERMAL DECOMPOSITION KINETICS OF URUSHIOL METAL CHELATE POLYMERS[J].Chinese Journal of Polymer Science,1994,{4}(04):358-365.DOI:
HU Binghuan, CHEN Riyao, LIN Jinhuo. STUDY ON THERMAL DECOMPOSITION KINETICS OF URUSHIOL METAL CHELATE POLYMERS*[J]. 1994, 12(4): 358-365.DOI:
STUDY ON THERMAL DECOMPOSITION KINETICS OF URUSHIOL METAL CHELATE POLYMERS*
urushiol-Nd and urushiol-Ti chelatepolymers has been studied by non-isothermal thermogravimetry. The results suggest that thethermal decomposition kinetics of three chelate polymers are all of first order. Their averageactivation energy values of the thermal decomposition calculated by Ozawa-(I) method are 110
79
136. 98 and 163. 64 kJ mol
-1
respectively
which increase linearly with the metal valence of themetal chelate polymers
Abstract
The thermal decomposition kinetics of urushiol-Cu
urushiol-Nd and urushiol-Ti chelatepolymers has been studied by non-isothermal thermogravimetry. The results suggest that thethermal decomposition kinetics of three chelate polymers are all of first order. Their averageactivation energy values of the thermal decomposition calculated by Ozawa-(I) method are 110
79
136. 98 and 163. 64 kJ mol
-1
respectively
which increase linearly with the metal valence of themetal chelate polymers
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