GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*
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GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*
Vol. 12, Issue 2, Pages: 137-144(1994)
Affiliations:
1. Department of Chemistry
2. Peking University
3. Beijing 100871
Author bio:
Funds:
DOI:
CLC:TQ316.6
Published:20 June 1994
Accepted:
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[1]王伟,丘坤元,冯新德.GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT[J].Chinese Journal of Polymer Science,1994,{4}(02):137-144.
WANG Wei, QIU Kunyuan, FENG Xinde. GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*[J]. 1994, 12(2): 137-144.
[1]王伟,丘坤元,冯新德.GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT[J].Chinese Journal of Polymer Science,1994,{4}(02):137-144.DOI:
WANG Wei, QIU Kunyuan, FENG Xinde. GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*[J]. 1994, 12(2): 137-144.DOI:
GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*
<正> Two copolymers containing p-tolylcarbamoyl pendant group poly (MAMT-co-VAc) and poly(MAMT-co-MA) were synthesized f and the graft copolymerization of AAM onto these two func-tional copolymers films initiated with ceric salt were carried out in aqueous solution for variousperiods at 30℃. The formation of graft copolymer was verified by water absorption
ESCA andSEM photographs. Based on the results of the study of the initiation mechanism of model com-pounds and ceric salt systems
the reaction mechanism of the graft copolymerization initiated withceric salt was proposed.
Abstract
Two copolymers containing p-tolylcarbamoyl pendant group poly (MAMT-co-VAc) and poly(MAMT-co-MA) were synthesized f and the graft copolymerization of AAM onto these two func-tional copolymers films initiated with ceric salt were carried out in aqueous solution for variousperiods at 30℃. The formation of graft copolymer was verified by water absorption
ESCA andSEM photographs. Based on the results of the study of the initiation mechanism of model com-pounds and ceric salt systems
the reaction mechanism of the graft copolymerization initiated withceric salt was proposed.
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