COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*

CHEN Chuanfu; REN Changy; XI Fu

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COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*

Papers | Updated：2021-06-21

- COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*
- Vol. 12, Issue 2, Pages: 190-192(1994)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  CLC： O631.5
- Published：20 June 1994
- Accepted：
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[1]陈传福,任长玉,习复.COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR[J].Chinese Journal of Polymer Science,1994,{4}(02):190-193.

CHEN Chuanfu, REN Changy, XI Fu. COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*[J]. 1994, 12(2): 190-192.
[1]陈传福,任长玉,习复.COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR[J].Chinese Journal of Polymer Science,1994,{4}(02):190-193. DOI：

CHEN Chuanfu, REN Changy, XI Fu. COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*[J]. 1994, 12(2): 190-192. DOI：

摘要

<正> The copolymerization process of triphenylmethyl methacrylate （TrMA） and methylmethacrylate （MMA） using chiral anionic complex initiator （-） SP-FlLi （Scheme 1） has beenstudied in toluene and THF

respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure

respectively.

Abstract

The copolymerization process of triphenylmethyl methacrylate （TrMA） and methylmethacrylate （MMA） using chiral anionic complex initiator （-） SP-FlLi （Scheme 1） has beenstudied in toluene and THF

respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure

respectively.

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