SYNTHESIS AND FREE RADICAL POLYMERIZATION OF 2-OXO-3-METHYLEN E-5-PHENYL-1,4-DIOXAN

FENG Pinzhen

Your Location：

Home >

Browse articles >

SYNTHESIS AND FREE RADICAL POLYMERIZATION OF 2-OXO-3-METHYLEN E-5-PHENYL-1,4-DIOXAN

Papers | Updated：2021-06-21

- SYNTHESIS AND FREE RADICAL POLYMERIZATION OF 2-OXO-3-METHYLEN E-5-PHENYL-1,4-DIOXAN
- Vol. 11, Issue 2, Pages: 153-157(1993)
- Affiliations：
  
  1. Chemistry Department, Graduate School, Academia Sinica,Beijing,100039
  2.   Graduate School
  3.   Academia Sinica
  4.   Beijing
  5.   100039
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 June 1993
- Accepted：
Scan QR Code
[1]冯品珍.SYNTHESIS AND FREE RADICAL POLYMERIZATION OF 2-OXO-3-METHYLEN E-5-PHENYL-1,4-DIOXAN[J].Chinese Journal of Polymer Science,1993,{4}(02):153-157.

FENG Pinzhen. SYNTHESIS AND FREE RADICAL POLYMERIZATION OF 2-OXO-3-METHYLEN E-5-PHENYL-1,4-DIOXAN[J]. 1993, 11(2): 153-157.
[1]冯品珍.SYNTHESIS AND FREE RADICAL POLYMERIZATION OF 2-OXO-3-METHYLEN E-5-PHENYL-1,4-DIOXAN[J].Chinese Journal of Polymer Science,1993,{4}(02):153-157. DOI：

FENG Pinzhen. SYNTHESIS AND FREE RADICAL POLYMERIZATION OF 2-OXO-3-METHYLEN E-5-PHENYL-1,4-DIOXAN[J]. 1993, 11(2): 153-157. DOI：

摘要

正

The novel cyclic monomer

2-oxo-3-methylene-5-phenyl-1

4-dioxan

was synthesized by a set of reactions. Several intermediates were prepared and characterized in order to determine the monomer structure. The presence of chiral centers in the intermediates and resulting monomer makes it complicated to separate

purify and characterize them. It is a very reactive monomer which will polymerize even at room temperature if expose to moisture and air. This monomer can undergo essentially quantitative flee radical ring opening polymerization. The driving force for ring opening is the formation of new carbonyl group and benzylic radical. The monomer and polymer structure were established by IR

H NMR

C NMR and elemental analysis or high resolution mass spectrum. The molecular weight of the resulting polymer was estimated by viscosity determination.

Abstract

The novel cyclic monomer

2-oxo-3-methylene-5-phenyl-1

4-dioxan

H NMR

C NMR and elemental analysis or high resolution mass spectrum. The molecular weight of the resulting polymer was estimated by viscosity determination.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility

Related Author

No data

Related Institution

No data

⁰