A NEW TYPE OF CROWN FUNCTIONALIZED POLYSILOXANE AND ITS PLATINUM COMPLEX

CHEN Yuanyin; HONG Liwu; LI Jun; LU Xueran

Your Location：

Home >

Browse articles >

A NEW TYPE OF CROWN FUNCTIONALIZED POLYSILOXANE AND ITS PLATINUM COMPLEX

Papers | Updated：2021-06-21

- A NEW TYPE OF CROWN FUNCTIONALIZED POLYSILOXANE AND ITS PLATINUM COMPLEX
- Vol. 11, Issue 1, Pages: 54-58(1993)
- Affiliations：
  
  1. Department of Chemistry, Wuhan University,Wuhan,430072
  2. Wuhan University
  3. Wuhan 430072
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 March 1993
- Accepted：
Scan QR Code
[1]陈远荫,洪利武,李军,卢雪然.A NEW TYPE OF CROWN FUNCTIONALIZED POLYSILOXANE AND ITS PLATINUM COMPLEX[J].Chinese Journal of Polymer Science,1993,{4}(01):54-58.

CHEN Yuanyin, HONG Liwu, LI Jun, et al. A NEW TYPE OF CROWN FUNCTIONALIZED POLYSILOXANE AND ITS PLATINUM COMPLEX[J]. 1993, 11(1): 54-58.
[1]陈远荫,洪利武,李军,卢雪然.A NEW TYPE OF CROWN FUNCTIONALIZED POLYSILOXANE AND ITS PLATINUM COMPLEX[J].Chinese Journal of Polymer Science,1993,{4}(01):54-58. DOI：

CHEN Yuanyin, HONG Liwu, LI Jun, et al. A NEW TYPE OF CROWN FUNCTIONALIZED POLYSILOXANE AND ITS PLATINUM COMPLEX[J]. 1993, 11(1): 54-58. DOI：

摘要

正

A new type of crown functionalized polysiloxane

in which the crown moieties were incorporated into main chain

and its platinum complex were synthesized. The polysiloxane was synthesized from 3

16-dihydroxy-1- thia - 5

14- tetraoxacycloheptadecane via etheritication with ω-chloroundecene

followed by hydrosilylation with triethoxysilane

cohydrolysis with D

sequentially. Treating the polysiloxane with potassium cholroplatinite

the title complex was obtained. It was found that the platinum complex exhibited high catalytic activity in the hydrosilylation of olefins with triethoxysilane.

Abstract

A new type of crown functionalized polysiloxane

in which the crown moieties were incorporated into main chain

and its platinum complex were synthesized. The polysiloxane was synthesized from 3

16-dihydroxy-1- thia - 5

14- tetraoxacycloheptadecane via etheritication with ω-chloroundecene

followed by hydrosilylation with triethoxysilane

cohydrolysis with D

sequentially. Treating the polysiloxane with potassium cholroplatinite

the title complex was obtained. It was found that the platinum complex exhibited high catalytic activity in the hydrosilylation of olefins with triethoxysilane.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Related Author

No data

Related Institution

No data

⁰