SYNTHETI C STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅳ. SYNTHESIS, CHARACTERIZATION AND ANTITHROMBOGENICITY OF POLY-[N, N'( p,p-OXYDIPHENYLENE)] PYROMELLITIMIDE-POLYDIMETHYLDIPHENYLSILOXANE SEGMENTED COPOLYMER

LIN Sicong; ZHAO Xiaobin; ZHOU Caihua; TU Xiangtong

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SYNTHETI C STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅳ. SYNTHESIS, CHARACTERIZATION AND ANTITHROMBOGENICITY OF POLY-[N, N'( p,p-OXYDIPHENYLENE)] PYROMELLITIMIDE-POLYDIMETHYLDIPHENYLSILOXANE SEGMENTED COPOLYMER

Papers | Updated：2021-06-21

- SYNTHETI C STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅳ. SYNTHESIS, CHARACTERIZATION AND ANTITHROMBOGENICITY OF POLY-[N, N'( p,p-OXYDIPHENYLENE)] PYROMELLITIMIDE-POLYDIMETHYLDIPHENYLSILOXANE SEGMENTED COPOLYMER
- Vol. 11, Issue 4, Pages: 300-306(1993)
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- Published：20 December 1993
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LIN Sicong, ZHAO Xiaobin, ZHOU Caihua, et al. SYNTHETI C STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅳ. SYNTHESIS, CHARACTERIZATION AND ANTITHROMBOGENICITY OF POLY-[N, N'( p,p-OXYDIPHENYLENE)] PYROMELLITIMIDE-POLYDIMETHYLDIPHENYLSILOXANE SEGMENTED COPOLYMER[J]. 1993, 11(4): 300-306.
DOI：

LIN Sicong, ZHAO Xiaobin, ZHOU Caihua, et al. SYNTHETI C STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅳ. SYNTHESIS, CHARACTERIZATION AND ANTITHROMBOGENICITY OF POLY-[N, N'( p,p-OXYDIPHENYLENE)] PYROMELLITIMIDE-POLYDIMETHYLDIPHENYLSILOXANE SEGMENTED COPOLYMER[J]. 1993, 11(4): 300-306. DOI：

摘要

A novel class of aromatic polyimide-silicone segmented copolymer was synthesized with α

ω-bis (γ-aminopropyl) polydimethyldiphenylsiloxane (APMPS) as a silicone segment precursor

from which the segmented polyamic acid-b-silicone intermediate could be prepared simply with DMF as solvent. The segmented copolymer displays microphase separation and exhibits improved antithrombogenicity

which depends mainly upon both the content level and the DP of the silicone segment. Thermal stability and mechanical property of the copolymer are between that of the aromatic polyimide and the silicone

and also relate to both the content level and the DP of the silicone segment.

Abstract

A novel class of aromatic polyimide-silicone segmented copolymer was synthesized with α

ω-bis (γ-aminopropyl) polydimethyldiphenylsiloxane (APMPS) as a silicone segment precursor

and also relate to both the content level and the DP of the silicone segment.

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