STUDY ON POLYMERIZATION MECHANISM OF 3, 9,-DIALLYL-3, 9, -DIBENZYL-1, 5, 7, 11-TETRAOXASPIRO [5, 5] UNDECANE*

BAI Ruke; HU Yue; ZOU Yingfang; PAN Caiyuan; Toshiyuki; Uryu

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STUDY ON POLYMERIZATION MECHANISM OF 3, 9,-DIALLYL-3, 9, -DIBENZYL-1, 5, 7, 11-TETRAOXASPIRO [5, 5] UNDECANE*

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- STUDY ON POLYMERIZATION MECHANISM OF 3, 9,-DIALLYL-3, 9, -DIBENZYL-1, 5, 7, 11-TETRAOXASPIRO [5, 5] UNDECANE*
- Vol. 10, Issue 4, Pages: 343-349(1992)
- Affiliations：
  
  1. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, China) Toshiyuki, Uryu
  2.   University of Science and Technology of China
  3.   Hefei
  4.   China
  5.   Institute of Industrial Science
  6.   University of Tokyo
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 December 1992
- Accepted：
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[1]白如科,胡悦,邹应芳,潘才元,Toshiyuki,Uryu.STUDY ON POLYMERIZATION MECHANISM OF 3, 9,-DIALLYL-3, 9, -DIBENZYL-1, 5, 7, 11-TETRAOXASPIRO [5, 5] UNDECANE[J].Chinese Journal of Polymer Science,1992,{4}(04):343-349.

BAI Ruke, HU Yue, ZOU Yingfang, et al. STUDY ON POLYMERIZATION MECHANISM OF 3, 9,-DIALLYL-3, 9, -DIBENZYL-1, 5, 7, 11-TETRAOXASPIRO [5, 5] UNDECANE*[J]. 1992, 10(4): 343-349.
[1]白如科,胡悦,邹应芳,潘才元,Toshiyuki,Uryu.STUDY ON POLYMERIZATION MECHANISM OF 3, 9,-DIALLYL-3, 9, -DIBENZYL-1, 5, 7, 11-TETRAOXASPIRO [5, 5] UNDECANE[J].Chinese Journal of Polymer Science,1992,{4}(04):343-349. DOI：

BAI Ruke, HU Yue, ZOU Yingfang, et al. STUDY ON POLYMERIZATION MECHANISM OF 3, 9,-DIALLYL-3, 9, -DIBENZYL-1, 5, 7, 11-TETRAOXASPIRO [5, 5] UNDECANE*[J]. 1992, 10(4): 343-349. DOI：

摘要

正

A new monomer

9-diallyl-3

9-dibenzyl-1

11 - tetraoxa- spiro [5

5] undecane （6） was prepared by the reaction of 2- allyl- 2’ - benzyl- propanediol - 1.3 with dibutyltin oxide

and then treated with CS

. Monomer 4 could be initiated by cationic initiators to give a viscous polymer （white powder in the case of polymerization at 0℃）. Upon the NMR and IR spectra of the obtained polymer

the components and their relative amount were estimated. The polymerization mechanism was discussed.

Abstract

A new monomer

9-diallyl-3

9-dibenzyl-1

11 - tetraoxa- spiro [5

5] undecane （6） was prepared by the reaction of 2- allyl- 2’ - benzyl- propanediol - 1.3 with dibutyltin oxide

and then treated with CS

. Monomer 4 could be initiated by cationic initiators to give a viscous polymer （white powder in the case of polymerization at 0℃）. Upon the NMR and IR spectra of the obtained polymer

the components and their relative amount were estimated. The polymerization mechanism was discussed.

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