VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS

QIU Kunyuan; LU Zhihua; TANG Aijun; FENG Xinde

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VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS

Papers | Updated：2021-06-21

- VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS
- Vol. 10, Issue 4, Pages: 366-371(1992)
- Affiliations：
  
  1. Department of Chemistry, Peking University,Beijing,100871
  2. Peking University
  3. Beijing 100871
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 December 1992
- Accepted：
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[1]丘坤元,鲁志华,唐爱军,冯新德.VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS[J].Chinese Journal of Polymer Science,1992,{4}(04):366-371.

QIU Kunyuan, LU Zhihua, TANG Aijun, et al. VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS[J]. 1992, 10(4): 366-371.
[1]丘坤元,鲁志华,唐爱军,冯新德.VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS[J].Chinese Journal of Polymer Science,1992,{4}(04):366-371. DOI：

QIU Kunyuan, LU Zhihua, TANG Aijun, et al. VINYL RADICAL POLYMERIZATION INITIATED WITH CERIC ION AND N-(SUBSTITUTED PHENYL) ACETAMIDE SYSTEMS[J]. 1992, 10(4): 366-371. DOI：

摘要

正

The polymerization of acrylamide （AAM）in H

O/DMF or in H

O/CH

CN mixed solvent initiated with ceric ion (Ce

)/N-（substituted phenyl）-acetamide systems have been studied. The redox polymerization was revealed by the low value of overall activation energy （E

） of AAM polymerization using ceric ion/N-（substituted phenyl） acetamide system as an initiator. The end group of polymer formed was detected by IR spectrum analysis method

it revealed the presence of N-（m-acetoxy-methylphenyl） acetamide （m-AAe） moiety end group in the polymer obtained with ceric ion/m-AAe initiation system.

Abstract

The polymerization of acrylamide （AAM）in H

O/DMF or in H

O/CH

CN mixed solvent initiated with ceric ion (Ce

)/N-（substituted phenyl）-acetamide systems have been studied. The redox polymerization was revealed by the low value of overall activation energy （E

） of AAM polymerization using ceric ion/N-（substituted phenyl） acetamide system as an initiator. The end group of polymer formed was detected by IR spectrum analysis method

it revealed the presence of N-（m-acetoxy-methylphenyl） acetamide （m-AAe） moiety end group in the polymer obtained with ceric ion/m-AAe initiation system.

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