THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION

QIU Kunyuan; ZHANG Zhanghua; FENG Xinde

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THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION

Papers | Updated：2021-06-21

- THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION
- Vol. 10, Issue 3, Pages: 250-257(1992)
- Affiliations：
  
  1. Department of Chemistry, Peking University,Beijing,100871
  2. Peking University
  3. Beijing 100871
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1992
- Accepted：
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[1]丘坤元,张璋华,冯新德.THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION[J].Chinese Journal of Polymer Science,1992,{4}(03):250-257.

QIU Kunyuan, ZHANG Zhanghua, FENG Xinde. THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION[J]. 1992, 10(3): 250-257.
[1]丘坤元,张璋华,冯新德.THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION[J].Chinese Journal of Polymer Science,1992,{4}(03):250-257. DOI：

QIU Kunyuan, ZHANG Zhanghua, FENG Xinde. THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION[J]. 1992, 10(3): 250-257. DOI：

摘要

<正> The effects of N-2-hydroxyethyl-N-methyl-p-toluidine （HMT） on MMA polymerization using organic peroxide as an initiator and on AN photoinduced polymerization have been investigated respectively. The kinetics of polymerization and the overall activation energy of polymerization were determined. Based on kinetics study and the end group analysis of the polymer obtained by UV spectrum method

the initiation mechanism is proposed.

Abstract

The effects of N-2-hydroxyethyl-N-methyl-p-toluidine （HMT） on MMA polymerization using organic peroxide as an initiator and on AN photoinduced polymerization have been investigated respectively. The kinetics of polymerization and the overall activation energy of polymerization were determined. Based on kinetics study and the end group analysis of the polymer obtained by UV spectrum method

the initiation mechanism is proposed.

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