EFFECT OF HOT STRETCHING ON THE STRUCTURE OF POLYIMIDE FROM 1,4--BIS (3', 4'--DICARBOXYPHENOXY) BENZENE AND 4,4'-OXYDIANILINE
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EFFECT OF HOT STRETCHING ON THE STRUCTURE OF POLYIMIDE FROM 1,4--BIS (3', 4'--DICARBOXYPHENOXY) BENZENE AND 4,4'-OXYDIANILINE
Vol. 10, Issue 1, Pages: 20-25(1992)
Affiliations:
1. Polymer Physics Laboratory, Changchun Institute of Applied Chemistry, Academia Sinica,Changchun,130022
2. Changchun Institute of Applied Chemistry
3. Academia Sinica
4. Changchun 130022
5. Fomerly E.I.L.Voong and Voong Tse-Lieu
Author bio:
Funds:
DOI:
CLC:
Published:20 March 1992
Accepted:
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[1]孙振华,丁孟贤,冯之榴.EFFECT OF HOT STRETCHING ON THE STRUCTURE OF POLYIMIDE FROM 1,4--BIS (3', 4'--DICARBOXYPHENOXY) BENZENE AND 4,4'-OXYDIANILINE[J].Chinese Journal of Polymer Science,1992,{4}(01):20-25.
SUN Zhenhua, DING Mengxian, FENG Zhiliu. EFFECT OF HOT STRETCHING ON THE STRUCTURE OF POLYIMIDE FROM 1,4--BIS (3', 4'--DICARBOXYPHENOXY) BENZENE AND 4,4'-OXYDIANILINE[J]. 1992, 10(1): 20-25.
[1]孙振华,丁孟贤,冯之榴.EFFECT OF HOT STRETCHING ON THE STRUCTURE OF POLYIMIDE FROM 1,4--BIS (3', 4'--DICARBOXYPHENOXY) BENZENE AND 4,4'-OXYDIANILINE[J].Chinese Journal of Polymer Science,1992,{4}(01):20-25.DOI:
SUN Zhenhua, DING Mengxian, FENG Zhiliu. EFFECT OF HOT STRETCHING ON THE STRUCTURE OF POLYIMIDE FROM 1,4--BIS (3', 4'--DICARBOXYPHENOXY) BENZENE AND 4,4'-OXYDIANILINE[J]. 1992, 10(1): 20-25.DOI:
EFFECT OF HOT STRETCHING ON THE STRUCTURE OF POLYIMIDE FROM 1,4--BIS (3', 4'--DICARBOXYPHENOXY) BENZENE AND 4,4'-OXYDIANILINE
4’-oxydianiline film specimens before and after hot stretching has been investigated by WAXD
DSC and FTIR. As evidenced by both the WAXD and DSC results
it could be believed that strain induced crystallization did take place after hot stretching. Meanwhile
shifting position and splitting of some band peaks existed on the FTIR spectrograms were explained in terms of the close packing of chains and the changes of inter-molecular charge-transfer interaction between imide groups and aromatic groups upon crystallization.
Abstract
The structure of polyimide from 1
4-bis (3’
4’-dicarboxyphenoxy) benzene and 4
4’-oxydianiline film specimens before and after hot stretching has been investigated by WAXD
DSC and FTIR. As evidenced by both the WAXD and DSC results
it could be believed that strain induced crystallization did take place after hot stretching. Meanwhile
shifting position and splitting of some band peaks existed on the FTIR spectrograms were explained in terms of the close packing of chains and the changes of inter-molecular charge-transfer interaction between imide groups and aromatic groups upon crystallization.
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