THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E

ZHANG Tingli; HU Rongzu; ZHANG Mingnan; WANG Yaping; LIANG Yanjun; WANG Yuan

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THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E

Papers | Updated：2021-06-21

- THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E
- Vol. 9, Issue 1, Pages: 19-23(1991)
- Affiliations：
  
  1. Xian Modern Chemistry Research Institute, Xian,710061
  2. Xian 710061
  3. Xian Xian 710061 ,710061
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 March 1991
- Accepted：
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[1]张廷理,胡荣祖,张明南,王亚平,梁燕军,汪渊.THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORIDE[J].Chinese Journal of Polymer Science,1991,{4}(01):19-23.

ZHANG Tingli, HU Rongzu, ZHANG Mingnan, et al. THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E[J]. 1991, 9(1): 19-23.
[1]张廷理,胡荣祖,张明南,王亚平,梁燕军,汪渊.THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORIDE[J].Chinese Journal of Polymer Science,1991,{4}(01):19-23. DOI：

ZHANG Tingli, HU Rongzu, ZHANG Mingnan, et al. THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E[J]. 1991, 9(1): 19-23. DOI：

摘要

正

The polymerization thermokinetics of pyrrole in the presence of iron trichloride art studied by using a Calvet microcalorimoter. The apparent activation energy

the pre-exponential constant and reaction order of this reaction in the temperature range of 25.2—37℃are 34.5 KJ·mol

-1

2.74

-1

and 1 respectively. The activation free-energies of this reaction at 25.2°

30°and 37℃are 91.8

92.9 and 94.2 KJ·mol

-1

respectively.

Abstract

The polymerization thermokinetics of pyrrole in the presence of iron trichloride art studied by using a Calvet microcalorimoter. The apparent activation energy

the pre-exponential constant and reaction order of this reaction in the temperature range of 25.2—37℃ are 34.5 KJ·mol

-1

2.74

-1

and 1 respectively. The activation free-energies of this reaction at 25.2°

30°and 37℃ are 91.8

92.9 and 94.2 KJ·mol

-1

respectively.

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