THE PHOTOPOLYMERIZATION KINETICS OF PHOTOSENSITIZED ACRYLAMIDE SYSTEM INDUCED BY He-Ne LASER

FENG Minhui; LIANG Zhaoxi; CHEN Yonglie

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THE PHOTOPOLYMERIZATION KINETICS OF PHOTOSENSITIZED ACRYLAMIDE SYSTEM INDUCED BY He-Ne LASER

Papers | Updated：2021-06-21

- THE PHOTOPOLYMERIZATION KINETICS OF PHOTOSENSITIZED ACRYLAMIDE SYSTEM INDUCED BY He-Ne LASER
- Vol. 9, Issue 1, Pages: 24-30(1991)
- Affiliations：
  
  1. Institute of Polymer Science, Zhongshan University,Guangzhou
  2. Zhongshan University
  3. Zhongshan University Guangzhou
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 March 1991
- Accepted：
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[1]冯敏辉,梁兆熙,陈用烈.THE PHOTOPOLYMERIZATION KINETICS OF PHOTOSENSITIZED ACRYLAMIDE SYSTEM INDUCED BY He-Ne LASER[J].Chinese Journal of Polymer Science,1991,{4}(01):24-30.

FENG Minhui, LIANG Zhaoxi, CHEN Yonglie. THE PHOTOPOLYMERIZATION KINETICS OF PHOTOSENSITIZED ACRYLAMIDE SYSTEM INDUCED BY He-Ne LASER[J]. 1991, 9(1): 24-30.
[1]冯敏辉,梁兆熙,陈用烈.THE PHOTOPOLYMERIZATION KINETICS OF PHOTOSENSITIZED ACRYLAMIDE SYSTEM INDUCED BY He-Ne LASER[J].Chinese Journal of Polymer Science,1991,{4}(01):24-30. DOI：

FENG Minhui, LIANG Zhaoxi, CHEN Yonglie. THE PHOTOPOLYMERIZATION KINETICS OF PHOTOSENSITIZED ACRYLAMIDE SYSTEM INDUCED BY He-Ne LASER[J]. 1991, 9(1): 24-30. DOI：

摘要

<正> The kinetics of the photopolymerization of sensitized acrylamide （AM） system induced by He-Ne laser has been investigated. Using methylene blue （MB）-triethanolamine （TEOA） as the photosensitive system

the photopolymerization followed a nonsteady-state kinetic scheme in the initial period of polymerization （the monomer conversion C%<2%） and then followed a steady-state kinetic scheme （5% >C%>2%）. Accirding to the steady-state hypothesis

the mechanism of photopolymerization was proposed. The deduced kinetic equation of the photopolymerization of AM is in good coincidence with the experimental results.

Abstract

The kinetics of the photopolymerization of sensitized acrylamide （AM） system induced by He-Ne laser has been investigated. Using methylene blue （MB）-triethanolamine （TEOA） as the photosensitive system

the mechanism of photopolymerization was proposed. The deduced kinetic equation of the photopolymerization of AM is in good coincidence with the experimental results.

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