STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS*
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STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS*
Vol. 9, Issue 1, Pages: 31-38(1991)
Affiliations:
1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchum
2. Academia Sinica
3. Academia Sinica Changchun
Author bio:
Funds:
DOI:
CLC:
Published:20 March 1991
Accepted:
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[1]杜郢,韩孝族,刘文忠.STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS[J].Chinese Journal of Polymer Science,1991,{4}(01):31-38.
DU Ying, HAN Xiaozu, LIU Wenzhong. STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS*[J]. 1991, 9(1): 31-38.
[1]杜郢,韩孝族,刘文忠.STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS[J].Chinese Journal of Polymer Science,1991,{4}(01):31-38.DOI:
DU Ying, HAN Xiaozu, LIU Wenzhong. STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS*[J]. 1991, 9(1): 31-38.DOI:
STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS*
<正> Castor oil polyurethane/poly(methyl methacrylate) AB crosslinked polymers (ABCP) were synthesized by free radical copolymerization of MMA and vinyl-terminated castor oil polyurethane which was obtained from isocyanate-terminated castor oil polyurethane and hydroxyethyl methacrylate The mechanical properties
transition and relaxation
as well as compatibility and morphology of the ABCP were investigated by changing the component. The results show that the ABCP is a semicompatible system and the compatibility of the two components decreases with increasing content of the hard segment. The mechanical and damping properties of the ABCP are obviously superior to that of their homopolymers. The damping value is mainly controlled by cross[ink density of the ABCP but the T-g value by component.
Abstract
Castor oil polyurethane/poly(methyl methacrylate) AB crosslinked polymers (ABCP) were synthesized by free radical copolymerization of MMA and vinyl-terminated castor oil polyurethane which was obtained from isocyanate-terminated castor oil polyurethane and hydroxyethyl methacrylate The mechanical properties
transition and relaxation
as well as compatibility and morphology of the ABCP were investigated by changing the component. The results show that the ABCP is a semicompatible system and the compatibility of the two components decreases with increasing content of the hard segment. The mechanical and damping properties of the ABCP are obviously superior to that of their homopolymers. The damping value is mainly controlled by cross[ink density of the ABCP but the T-g value by component.
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