STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION

TANG Qi; ZONG Huijuan; CHEN Zonghan; JIANG Yingyan

Your Location：

Home >

Browse articles >

STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION

Papers | Updated：2021-06-21

- STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION
- Vol. 9, Issue 1, Pages: 39-47(1991)
- Affiliations：
  
  1. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui) CHEN Zonghan and JIANG Yingyan
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 March 1991
- Accepted：
Scan QR Code
[1]汤琪,宗惠娟,陈宗翰,江英彦.STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J].Chinese Journal of Polymer Science,1991,{4}(01):39-47.

TANG Qi, ZONG Huijuan, CHEN Zonghan, et al. STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J]. 1991, 9(1): 39-47.
[1]汤琪,宗惠娟,陈宗翰,江英彦.STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J].Chinese Journal of Polymer Science,1991,{4}(01):39-47. DOI：

TANG Qi, ZONG Huijuan, CHEN Zonghan, et al. STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J]. 1991, 9(1): 39-47. DOI：

摘要

正

Six kinds of polymer ligands

supported on SiO

containing coordinating atoms P

S and N respectively

have been synthesized. The Ru（Ⅲ）-Co（Ⅱ） bimetallic complexes of these polymer ligands have been obtained and examined as catalysts for the hydroformylation of cyclohexene. The effects of reaction temperature

pressure and Co/Ru ratio etc. on the activities of catalysts were investigated in detail. The catalysts are all polymer-noncarbonyl-metal complexes

easily to be prepared

active and stable. From the experimental results it can be suggested that under reaction conditions such polymer-noncarbonyl-metal complexes convert "in situ" to polymer-carbonyl-metal complexes

thus become active catalysts. The course of this conversion is supposed as a preliminary approach.

Abstract

Six kinds of polymer ligands

supported on SiO

containing coordinating atoms P

S and N respectively

pressure and Co/Ru ratio etc. on the activities of catalysts were investigated in detail. The catalysts are all polymer-noncarbonyl-metal complexes

easily to be prepared

active and stable. From the experimental results it can be suggested that under reaction conditions such polymer-noncarbonyl-metal complexes convert "in situ" to polymer-carbonyl-metal complexes

thus become active catalysts. The course of this conversion is supposed as a preliminary approach.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Related Author

No data

Related Institution

No data

⁰