A new kind of monomers was successfully synthesized by the reaction between 2-chloro methyl cycloketal and trimethylsilyl cyanide
followed by ring closure and dehaiogenation. Polymerizations of the monomers were carried out in benzene solution at 80℃with benzoyl peroxide as initiator. Both the structures of monomers and polymers were characterized by IR
1
H NMR
13
C NMR and elemental analysis.
Abstract
A new kind of monomers was successfully synthesized by the reaction between 2-chloro methyl cycloketal and trimethylsilyl cyanide
followed by ring closure and dehaiogenation. Polymerizations of the monomers were carried out in benzene solution at 80℃ with benzoyl peroxide as initiator. Both the structures of monomers and polymers were characterized by IR
1
H NMR
13
C NMR and elemental analysis.
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