ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE

XU Kang; DENG Zhenghua; WAN Guoxiang

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ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE

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- ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE
- Vol. 9, Issue 3, Pages: 232-237(1991)
- Affiliations：
  
  1. Chengdu Institute of Organic Chemistry, Academia Sinica,Chengdu
  2. Academia Sinica
  3. Chengdu
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1991
- Accepted：
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[1]许康,邓正华,万国祥.ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE[J].Chinese Journal of Polymer Science,1991,{4}(03):232-237.

XU Kang, DENG Zhenghua, WAN Guoxiang. ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE[J]. 1991, 9(3): 232-237.
[1]许康,邓正华,万国祥.ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE[J].Chinese Journal of Polymer Science,1991,{4}(03):232-237. DOI：

XU Kang, DENG Zhenghua, WAN Guoxiang. ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE[J]. 1991, 9(3): 232-237. DOI：

摘要

正

Poly （oligoether methacrylate-co-acrylonitrile） s

P （MEOn- AN）

with oligoether pendants of different lengths were synthesized and the ion conduction property of their Li-salt complexes was studied as the function of polymer structure. At proper copolymer composition

lithium concentration and pendant length

the ion conductivity reaches 7.0×10

-5

S/cm at ambient temperature

together with improved mechanical strength. The ion transport in the polymer media is assisted by segmental relaxation

which is confirmed both by the consistency between ion conductivity and T

and by the study of TSC.

Abstract

Poly （oligoether methacrylate-co-acrylonitrile） s

P （MEOn- AN）

lithium concentration and pendant length

the ion conductivity reaches 7.0×10

-5

S/cm at ambient temperature

together with improved mechanical strength. The ion transport in the polymer media is assisted by segmental relaxation

which is confirmed both by the consistency between ion conductivity and T

and by the study of TSC.

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