PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)*

LOU Jianfeng; WENG Zhixue; HUANG Zhiming; PAN Zuren

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PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)*

Papers | Updated：2021-06-21

- PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)*
- Vol. 9, Issue 3, Pages: 238-245(1991)
- Affiliations：
  
  1. Chemical Engineering Department, Zhejiang University,Hangzhou,310027
  2. Zhejiang University
  3. Hangzhou 310027
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1991
- Accepted：
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[1]楼剑锋,翁志学,黄志明,潘祖仁.PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)[J].Chinese Journal of Polymer Science,1991,{4}(03):238-245.

LOU Jianfeng, WENG Zhixue, HUANG Zhiming, et al. PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)*[J]. 1991, 9(3): 238-245.
[1]楼剑锋,翁志学,黄志明,潘祖仁.PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)[J].Chinese Journal of Polymer Science,1991,{4}(03):238-245. DOI：

LOU Jianfeng, WENG Zhixue, HUANG Zhiming, et al. PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)*[J]. 1991, 9(3): 238-245. DOI：

摘要

<正> Swelling capacity of vinyl chloride （VC） in chlorinated polyethylene （CPE） with 25—40 wt% Cl at temperature 30—57℃was studied and their relationships were correlated with Langmuir and Freundlich adsorption equations. A ternary phase diagram for VC-CPE-PVC was also established. In-situ polymerization conditions of CPE-g-VC were proposed and CPE content control was analyzed for the manufacturing process of CPE-g-VC graft product based on results of phase equilibrium study.

Abstract

Swelling capacity of vinyl chloride （VC） in chlorinated polyethylene （CPE） with 25—40 wt% Cl at temperature 30—57℃ was studied and their relationships were correlated with Langmuir and Freundlich adsorption equations. A ternary phase diagram for VC-CPE-PVC was also established. In-situ polymerization conditions of CPE-g-VC were proposed and CPE content control was analyzed for the manufacturing process of CPE-g-VC graft product based on results of phase equilibrium study.

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