THE EFFECT OF IRRADIATION ON THE POLYETHERKETONE WITH CARDO GROUP
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THE EFFECT OF IRRADIATION ON THE POLYETHERKETONE WITH CARDO GROUP
Vol. 9, Issue 2, Pages: 180-183(1991)
Affiliations:
1. Changchun Institute of Applied Chemistry, Academia Sinica,Changchun,130022
2. Academia Sinica
3. Changchun 130022
Author bio:
Funds:
DOI:
CLC:
Published:20 June 1991
Accepted:
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[1]张万喜,徐俊,闫美兰,薄淑琴,陈天禄.THE EFFECT OF IRRADIATION ON THE POLYETHERKETONE WITH CARDO GROUP[J].Chinese Journal of Polymer Science,1991,{4}(02):180-183.
ZHANG Wanxi, XU Jun, YAN Meilan, et al. THE EFFECT OF IRRADIATION ON THE POLYETHERKETONE WITH CARDO GROUP[J]. 1991, 9(2): 180-183.
[1]张万喜,徐俊,闫美兰,薄淑琴,陈天禄.THE EFFECT OF IRRADIATION ON THE POLYETHERKETONE WITH CARDO GROUP[J].Chinese Journal of Polymer Science,1991,{4}(02):180-183.DOI:
ZHANG Wanxi, XU Jun, YAN Meilan, et al. THE EFFECT OF IRRADIATION ON THE POLYETHERKETONE WITH CARDO GROUP[J]. 1991, 9(2): 180-183.DOI:
THE EFFECT OF IRRADIATION ON THE POLYETHERKETONE WITH CARDO GROUP
The effects of irradiation on the polyetherketone with cardo group (PEK-C) were studied. It was found that PEK-C can be crosslinked by irradiation under vacuum
while degradation reaction occurred in PEK-C at room temperature in the presence of air. Moreover. it was also found that Ts value of the crosslinked PEK-C at high temperature is higher than that at room temperature in the case of the same gel content
whose value is about 8℃higher than that of unirradiated PEK-C. The gelation dose of PEK-C at 300℃under vacuum is 1.5×10
4
Gy
which is about hundred times smaller than that at room temperature.
Abstract
The effects of irradiation on the polyetherketone with cardo group (PEK-C) were studied. It was found that PEK-C can be crosslinked by irradiation under vacuum
while degradation reaction occurred in PEK-C at room temperature in the presence of air. Moreover. it was also found that Ts value of the crosslinked PEK-C at high temperature is higher than that at room temperature in the case of the same gel content
whose value is about 8℃ higher than that of unirradiated PEK-C. The gelation dose of PEK-C at 300℃ under vacuum is 1.5×10
4
Gy
which is about hundred times smaller than that at room temperature.
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