HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*

HE Binlin; SUN Juntan; LI Hong; SANG Junjie

Your Location：

Home >

Browse articles >

HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*

Papers | Updated：2021-06-21

- HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*
- Vol. 8, Issue 2, Pages: 158-164(1990)
- Affiliations：
  
  1. Institute of Polymer Chemistry, Nankai University,Tianjin
  2. Nankai University
  3. Tianjin
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 June 1990
- Accepted：
Scan QR Code
[1]何炳林,孙君坦,李弘,桑俊杰.HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS[J].Chinese Journal of Polymer Science,1990,{4}(02):158-164.

HE Binlin, SUN Juntan, LI Hong, et al. HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*[J]. 1990, 8(2): 158-164.
[1]何炳林,孙君坦,李弘,桑俊杰.HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS[J].Chinese Journal of Polymer Science,1990,{4}(02):158-164. DOI：

HE Binlin, SUN Juntan, LI Hong, et al. HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*[J]. 1990, 8(2): 158-164. DOI：

摘要

正

A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh

（CO）

with several kinds of polymer supports such as crosslinked poly （N-vinylpyrrolidone）（PNVP） and crosslinked poly （ styrene-co-maleic anhydride）（PMAn）

and subsequently were used to catalyze the hydroformylation of olefins. The catalysts were characterized by IR

SEM and XPS. The influence of the supports structure and crosslinking

metal’s content and particle size of the supports on the catalysts hydroformylation properties was studied. The factors which affect the catalytic conversion were also examined. The experimental results show that the polymer-supported Rh cluster catalysts possess very high catalytic activity and aldehyde selectivity as well as good reproducibility.

Abstract

A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh

（CO）

with several kinds of polymer supports such as crosslinked poly （N-vinylpyrrolidone）（PNVP） and crosslinked poly （ styrene-co-maleic anhydride）（PMAn）

and subsequently were used to catalyze the hydroformylation of olefins. The catalysts were characterized by IR

SEM and XPS. The influence of the supports structure and crosslinking

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Alternating Poly(ether-alt-ester)s with High Glass Transition Temperature Enabled by Rotationally Constrained Biaryl Units

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

Related Author

No data

Related Institution

No data

⁰