CHARGE-TRANSFER AND ENERGY-TRANSFER IN THE PHOTO-INDUCED COPOLYMERIZATION OF 2-VINYLNAPHTHALENE WITH MALEIC ANHYDRIDE*

LI Tong; LUO Bin; LI Shanjun; CHU Guobei

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CHARGE-TRANSFER AND ENERGY-TRANSFER IN THE PHOTO-INDUCED COPOLYMERIZATION OF 2-VINYLNAPHTHALENE WITH MALEIC ANHYDRIDE*

Papers | Updated：2021-06-21

- CHARGE-TRANSFER AND ENERGY-TRANSFER IN THE PHOTO-INDUCED COPOLYMERIZATION OF 2-VINYLNAPHTHALENE WITH MALEIC ANHYDRIDE*
- Vol. 8, Issue 2, Pages: 170-176(1990)
- Affiliations：
  
  1. Department of Material Science, Fudan Unversity, Shanghai) CHU Guobei
  2.   Fudan Unversity
  3.   Shanghai
  4.   Department of Materials
  5.   Shanghai Institute of Building Materials
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 June 1990
- Accepted：
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[1]李橦,罗彬,李善君,储国蓓.CHARGE-TRANSFER AND ENERGY-TRANSFER IN THE PHOTO-INDUCED COPOLYMERIZATION OF 2-VINYLNAPHTHALENE WITH MALEIC ANHYDRIDE[J].Chinese Journal of Polymer Science,1990,{4}(02):170-176.

LI Tong, LUO Bin, LI Shanjun, et al. CHARGE-TRANSFER AND ENERGY-TRANSFER IN THE PHOTO-INDUCED COPOLYMERIZATION OF 2-VINYLNAPHTHALENE WITH MALEIC ANHYDRIDE*[J]. 1990, 8(2): 170-176.
[1]李橦,罗彬,李善君,储国蓓.CHARGE-TRANSFER AND ENERGY-TRANSFER IN THE PHOTO-INDUCED COPOLYMERIZATION OF 2-VINYLNAPHTHALENE WITH MALEIC ANHYDRIDE[J].Chinese Journal of Polymer Science,1990,{4}(02):170-176. DOI：

LI Tong, LUO Bin, LI Shanjun, et al. CHARGE-TRANSFER AND ENERGY-TRANSFER IN THE PHOTO-INDUCED COPOLYMERIZATION OF 2-VINYLNAPHTHALENE WITH MALEIC ANHYDRIDE*[J]. 1990, 8(2): 170-176. DOI：

摘要

<正> The initiation mechanism of the copolymerization of 2-vinylnaphthalene with maleic anhydride was studied under irradiation of 365 nm. The excited complex was formed from （1） the local excitation of 2-vinylnaphthalene followed by the charge-transfer interaction with maleic anhydride and （2） the excitation of the ground state charge-transfer complex

and then it collapsed to 1

4-tetramethylene biradical for initiation. A1: 1 alternating copolymer was formed in different monomer feeds. Addition of benzophenone could greatly enhance the rate of copolymerization through energy-transfer mechanism.

Abstract

The initiation mechanism of the copolymerization of 2-vinylnaphthalene with maleic anhydride was studied under irradiation of 365 nm. The excited complex was formed from （1） the local excitation of 2-vinylnaphthalene followed by the charge-transfer interaction with maleic anhydride and （2） the excitation of the ground state charge-transfer complex

and then it collapsed to 1

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