AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM

SUN Luying; HUANG Zhitang

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AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM

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- AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM
- Vol. 8, Issue 2, Pages: 177-182(1990)
- Affiliations：
  
  1. Institute of Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 June 1990
- Accepted：
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[1]孙录应,黄志镗.AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J].Chinese Journal of Polymer Science,1990,{4}(02):177-182.

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J]. 1990, 8(2): 177-182.
[1]孙录应,黄志镗.AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J].Chinese Journal of Polymer Science,1990,{4}(02):177-182. DOI：

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J]. 1990, 8(2): 177-182. DOI：

摘要

<正> The polymerization kinetics of 4

4′-biphenyldicarbonitrile using cuprous chloride-zinc system as catatyst was investigated. the concentration of unreacted cyano group was measured by infrared spectroscopic analysis using potassium ferricyanide as the internal reference. It was found that the polymerization rate is directly proportional to the concentrations ofcyano group

cuprous chloride and zinc

and the activation energy of the polymerization is as Tow as 18.4 KJ/mol. In addition

the other kinetics parameters were obtained and discussed.

Abstract

The polymerization kinetics of 4

cuprous chloride and zinc

and the activation energy of the polymerization is as Tow as 18.4 KJ/mol. In addition

the other kinetics parameters were obtained and discussed.

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