STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS

QIU Kunyuan; FU Jie GUO; Xinqiu; FENG Xinde

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STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS

Papers | Updated：2021-06-21

- STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS
- Vol. 8, Issue 2, Pages: 188-195(1990)
- Affiliations：
  
  1. Department of Chemistry, Peking University,Beijing
  2. Peking University
  3. Beijing
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 June 1990
- Accepted：
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[1]丘坤元,傅杰,郭新秋,冯新德.STUDIES ON ORGANIC PEROXIDE/N, NDI(2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J].Chinese Journal of Polymer Science,1990,{4}(02):188-195.

QIU Kunyuan, FU Jie GUO, Xinqiu, et al. STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J]. 1990, 8(2): 188-195.
[1]丘坤元,傅杰,郭新秋,冯新德.STUDIES ON ORGANIC PEROXIDE/N, NDI(2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J].Chinese Journal of Polymer Science,1990,{4}(02):188-195. DOI：

QIU Kunyuan, FU Jie GUO, Xinqiu, et al. STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J]. 1990, 8(2): 188-195. DOI：

摘要

正

The polymerization of methyl methacrylate （MMA） initiated by organic peroxide and polymerizable aromatic tertiary amine such as N

N-di （2-α-methylacryloyloxy propyl）-p-toluidine （MP）

PT binary system has been studied. It was found that the （MP）

PT promotes MMA polymerization

and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.

Abstract

The polymerization of methyl methacrylate （MMA） initiated by organic peroxide and polymerizable aromatic tertiary amine such as N

N-di （2-α-methylacryloyloxy propyl）-p-toluidine （MP）

PT binary system has been studied. It was found that the （MP）

PT promotes MMA polymerization

and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.

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