Three polycaprolactam samples modified by 0.05—0.50% polybenzimidazole (PBI) by weight were prepared. Their structure and mechanical properties were characterized by means of FT-IR
SEM
DTA
density tensile
impact and viscoelastic method. PBI delayed the superimposed polymerization-crystallization process of the activated anionic polymerization of caprolactam. The monomer casting (MC) nylons modified by PBI had lower crystallinities
lower T
g
and more nearly perfect spherulites than MC nylon itself
and showed a typical toughening effect.
Abstract
Three polycaprolactam samples modified by 0.05—0.50% polybenzimidazole (PBI) by weight were prepared. Their structure and mechanical properties were characterized by means of FT-IR
SEM
DTA
density tensile
impact and viscoelastic method. PBI delayed the superimposed polymerization-crystallization process of the activated anionic polymerization of caprolactam. The monomer casting (MC) nylons modified by PBI had lower crystallinities
lower T
g
and more nearly perfect spherulites than MC nylon itself
and showed a typical toughening effect.
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