INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)

HUANG Jiaxian; CHEN Guohua; EDDY TIJSMA; LEEN VAN DER DOES; ADRIAAN BANTJES

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INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)

Papers | Updated：2021-06-21

- INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)
- Vol. 8, Issue 3, Pages: 197-203(1990)
- Affiliations：
  
  1. Department of Chemical Technology, Biomaterials Section, Twente University, P. O. Box 217, Enschede7500 AE, The Netherlands) Present address: Nankai University, Department of Chemistry, Tianjin, People’s Republic of China
  2.   Department of Chemistry
  3.   Tianjin
  4.   People’s Republic of China
  5.   Department of Chemical Technology
  6.   Biomaterials Section
  7.   Twente University
  8.   P. O. Box 217
  9.    Enschede  ,7500 AE
  10.   The Netherlands
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1990
- Accepted：
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[1]黄家贤,陈国华,EDDY TIJSMA,LEEN VAN DER DOES,ADRIAAN BANTJES.INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)[J].Chinese Journal of Polymer Science,1990,{4}(03):197-203.

HUANG Jiaxian, CHEN Guohua, EDDY TIJSMA, et al. INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)[J]. 1990, 8(3): 197-203.
[1]黄家贤,陈国华,EDDY TIJSMA,LEEN VAN DER DOES,ADRIAAN BANTJES.INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)[J].Chinese Journal of Polymer Science,1990,{4}(03):197-203. DOI：

HUANG Jiaxian, CHEN Guohua, EDDY TIJSMA, et al. INVESTIGATIONS ON VINYLENE CARBONATE Ⅰ. PREPARATION AND PROPERTIES OF POLY-(VINYLENEC ARBONATE)[J]. 1990, 8(3): 197-203. DOI：

摘要

<正> Bulk polymerization of vinylene carbonate using t-butylperoxypivalate at 40℃gave colourless

high molecular weight poly（vinylene carbonate）（PVCA）. Solutions of PVCA in acetone and DMF are not stable at 25℃and this degradation was studied. From measurements in DMF with unfractionated PVCA a Mark-Houwink equation was obtained:

Abstract

Bulk polymerization of vinylene carbonate using t-butylperoxypivalate at 40℃ gave colourless

high molecular weight poly（vinylene carbonate）（PVCA）. Solutions of PVCA in acetone and DMF are not stable at 25℃ and this degradation was studied. From measurements in DMF with unfractionated PVCA a Mark-Houwink equation was obtained:

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