PHOTOCOPOLYMERIZATION OF MALEIC ANHYDRIDE AND VINYL ACETATE*

LI Xiaofang; LI Shanjun; QIN Anwei; YU Tongyin

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PHOTOCOPOLYMERIZATION OF MALEIC ANHYDRIDE AND VINYL ACETATE*

Papers | Updated：2021-06-21

- PHOTOCOPOLYMERIZATION OF MALEIC ANHYDRIDE AND VINYL ACETATE*
- Vol. 8, Issue 3, Pages: 261-268(1990)
- Affiliations：
  
  1. Department of Materials Science, Fudan University, Shanghai) Present address: Departraent of Chemistry, Shandong University,Jinan,China
  2.   Shandong University
  3.   Jinan
  4.   China
  5.   Department of Materials Science
  6.   Fudan University
  7.   Shanghai
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1990
- Accepted：
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[1]李小放,李善君,秦安慰,于同隐.PHOTOCOPOLYMERIZATION OF MALEIC ANHYDRIDE AND VINYL ACETATE[J].Chinese Journal of Polymer Science,1990,{4}(03):261-268.

LI Xiaofang, LI Shanjun, QIN Anwei, et al. PHOTOCOPOLYMERIZATION OF MALEIC ANHYDRIDE AND VINYL ACETATE*[J]. 1990, 8(3): 261-268.
[1]李小放,李善君,秦安慰,于同隐.PHOTOCOPOLYMERIZATION OF MALEIC ANHYDRIDE AND VINYL ACETATE[J].Chinese Journal of Polymer Science,1990,{4}(03):261-268. DOI：

LI Xiaofang, LI Shanjun, QIN Anwei, et al. PHOTOCOPOLYMERIZATION OF MALEIC ANHYDRIDE AND VINYL ACETATE*[J]. 1990, 8(3): 261-268. DOI：

摘要

<正> The charge-transfer complex of maleic anhydride and vinyl acetate was copolymerized under UV light. The chain composition and structure of the copolymer were analyzed with conductometry and NMR

and the chain sequence was determined as alternating. The copolymerization rates at different feed ratios

temperatures and in different solvents were investigated

giving evidence to the very active involvement of the CT complexes in the copolymerization. Terpolymerization with acrylonitrile also showed that the complex mechanism was a proper one for this system.

Abstract

The charge-transfer complex of maleic anhydride and vinyl acetate was copolymerized under UV light. The chain composition and structure of the copolymer were analyzed with conductometry and NMR

and the chain sequence was determined as alternating. The copolymerization rates at different feed ratios

temperatures and in different solvents were investigated

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