A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE

YUAN Guoqing; CHEN Yuying; CHEN Rongyao

Your Location：

Home >

Browse articles >

A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE

Papers | Updated：2021-06-21

- A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE
- Vol. 7, Issue 3, Pages: 219-224(1989)
- Affiliations：
  
  1. Institute of Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1989
- Accepted：
Scan QR Code
[1]袁国卿,陈予英,陈荣耀.A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J].Chinese Journal of Polymer Science,1989,{4}(03):219-224.

YUAN Guoqing, CHEN Yuying, CHEN Rongyao. A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J]. 1989, 7(3): 219-224.
[1]袁国卿,陈予英,陈荣耀.A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J].Chinese Journal of Polymer Science,1989,{4}(03):219-224. DOI：

YUAN Guoqing, CHEN Yuying, CHEN Rongyao. A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J]. 1989, 7(3): 219-224. DOI：

摘要

<正> A series of porous microspheres of linear and ethylene diacrylate （M’） cross-linked copolymers of 2-vinylpyridine （V） and methyl acrylate （M） reacted with tetracarbonyldichlorodirhodium to form a series of cis-dicarbonylrhodium chelate complex （MVRh and MVM ’Rh）. They are thermally stable yet very reactive in the carbonylation of methanol to acetic acid

and of methanol-acetic acid mixture to acetic acid and acetic anhydride with a selectivity of 100% under relatively mild and anhydrous conditions.

Abstract

A series of porous microspheres of linear and ethylene diacrylate （M’） cross-linked copolymers of 2-vinylpyridine （V） and methyl acrylate （M） reacted with tetracarbonyldichlorodirhodium to form a series of cis-dicarbonylrhodium chelate complex （MVRh and MVM ’Rh）. They are thermally stable yet very reactive in the carbonylation of methanol to acetic acid

and of methanol-acetic acid mixture to acetic acid and acetic anhydride with a selectivity of 100% under relatively mild and anhydrous conditions.

关键词

Keywords

references

Views

234

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Related Author

No data

Related Institution

No data

⁰