COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER

XUE Gi; DAI Qinpin; DING Jianfu; WU Peiyi

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COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER

Papers | Updated：2021-06-21

- COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER
- Vol. 7, Issue 3, Pages: 239-244(1989)
- Affiliations：
  
  1. Department of Chemistry, Nanjing University,Nanjing
  2. Nanjing University
  3. Nanjing.
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1989
- Accepted：
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[1]薛奇,戴庆平,丁建夫,武培怡.COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER[J].Chinese Journal of Polymer Science,1989,{4}(03):239-244.

XUE Gi, DAI Qinpin, DING Jianfu, et al. COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER[J]. 1989, 7(3): 239-244.
[1]薛奇,戴庆平,丁建夫,武培怡.COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER[J].Chinese Journal of Polymer Science,1989,{4}(03):239-244. DOI：

XUE Gi, DAI Qinpin, DING Jianfu, et al. COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER[J]. 1989, 7(3): 239-244. DOI：

摘要

<正> The coordination polymerization of benzotriazole with metallic copper has been investigated by infrared and X-ray photoelectron spectroscopies. We found that benzotriazole could react with copper （0） under mild conditions to form bis （benzotriazolato） copper （Ⅱ） and benzotriazolato copper （Ⅰ）which covered the surface of copper metal in the shape of polymeric materials. Since benzotriazole is of great interest as a ligand in that its presence in many biological system with metal ions

and is considered as a corrosion inhibitor

this work will be in favour of the study of protective corrosion.

Abstract

The coordination polymerization of benzotriazole with metallic copper has been investigated by infrared and X-ray photoelectron spectroscopies. We found that benzotriazole could react with copper （0） under mild conditions to form bis （benzotriazolato） copper （Ⅱ） and benzotriazolato copper （Ⅰ）which covered the surface of copper metal in the shape of polymeric materials. Since benzotriazole is of great interest as a ligand in that its presence in many biological system with metal ions

and is considered as a corrosion inhibitor

this work will be in favour of the study of protective corrosion.

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