AROMATIC AND HETEROCYCLIC DINITRILES AND THEIR POLYMERS ⅪⅤ. STUDY ON THE CATALYSTS OF THE POLYMERIZATION OF AROMATIC NITRILES*

SUN Luying; HUANG Zhitang

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AROMATIC AND HETEROCYCLIC DINITRILES AND THEIR POLYMERS ⅪⅤ. STUDY ON THE CATALYSTS OF THE POLYMERIZATION OF AROMATIC NITRILES*

Papers | Updated：2021-06-21

- AROMATIC AND HETEROCYCLIC DINITRILES AND THEIR POLYMERS ⅪⅤ. STUDY ON THE CATALYSTS OF THE POLYMERIZATION OF AROMATIC NITRILES*
- Vol. 7, Issue 1, Pages: 38-44(1989)
- Affiliations：
  
  1. Institute of Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Academia Sinica Beijing
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 March 1989
- Accepted：
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[1]孙录应,黄镗.AROMATIC AND HETEROCYCLIC DINITRILES AND THEIR POLYMERS ⅪⅤ.STUDY ON THE CATALYSTS OF THE POLYMERIZATION OF AROMATIC NITRILES[J].Chinese Journal of Polymer Science,1989,{4}(01):38-44.

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC DINITRILES AND THEIR POLYMERS ⅪⅤ. STUDY ON THE CATALYSTS OF THE POLYMERIZATION OF AROMATIC NITRILES*[J]. 1989, 7(1): 38-44.
[1]孙录应,黄镗.AROMATIC AND HETEROCYCLIC DINITRILES AND THEIR POLYMERS ⅪⅤ.STUDY ON THE CATALYSTS OF THE POLYMERIZATION OF AROMATIC NITRILES[J].Chinese Journal of Polymer Science,1989,{4}(01):38-44. DOI：

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC DINITRILES AND THEIR POLYMERS ⅪⅤ. STUDY ON THE CATALYSTS OF THE POLYMERIZATION OF AROMATIC NITRILES*[J]. 1989, 7(1): 38-44. DOI：

摘要

<正> Various catalysts for the polymerization ot aromatic nitriles were investigated. It was found that Lewis acid-metal is a preferable catalyst system for the polymerization of aromatic nitriles

and the polymerization rate is about 10 times faster than Lewis acid alone. The polymerization rate of benzonitrile catalyzed by Lewis acid and different metals was measured

and the activity of metals was in the following decreasing order

magnesium

zinc

sodium

calcium. Furthermore

the polymerization of benzonitrile catalyzed by different Lewis acid and zinc was also investigated.

Abstract

Various catalysts for the polymerization ot aromatic nitriles were investigated. It was found that Lewis acid-metal is a preferable catalyst system for the polymerization of aromatic nitriles

and the polymerization rate is about 10 times faster than Lewis acid alone. The polymerization rate of benzonitrile catalyzed by Lewis acid and different metals was measured

and the activity of metals was in the following decreasing order

magnesium

zinc

sodium

calcium. Furthermore

the polymerization of benzonitrile catalyzed by different Lewis acid and zinc was also investigated.

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