GAS SORPTION AND TRANSPORT IN POLY (PHENYLENE OXIDE)(PPO)AND ARYL-BROMINATED PPO MEMBRANES

JIA Lianda; F. R. SHEU; R.T.CHERN; H.B.HOPFENBERG

Your Location：

Home >

Browse articles >

GAS SORPTION AND TRANSPORT IN POLY (PHENYLENE OXIDE)(PPO)AND ARYL-BROMINATED PPO MEMBRANES

Papers | Updated：2021-06-21

- GAS SORPTION AND TRANSPORT IN POLY (PHENYLENE OXIDE)(PPO)AND ARYL-BROMINATED PPO MEMBRANES
- Vol. 7, Issue 4, Pages: 306-314(1989)
- Affiliations：
  
  1. Chanochun Institute of Applied Chemistry, Academia Sinica, Chanochun, PRC) F. R. SHEU, R. T. CHERN and H. B. HOPFENBERG
  2.   Academia Sinica
  3.   PRC
  4.   Department of Chemical Engineering
  5.   North Carolina State University
  6.   Raleigh
  7.   NC 27695
  8.   USA
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 December 1989
- Accepted：
Scan QR Code
[1]贾连达,F. R. SHEU,R.T.CHERN,H.B.HOPFENBERG.GAS SORPTION AND TRANSPORT IN POLY (PHENYLENE OXIDE)(PPO)AND ARYL-BROMINATED PPO MEMBRANES[J].Chinese Journal of Polymer Science,1989,{4}(04):306-314.

JIA Lianda, F. R. SHEU, R.T.CHERN, et al. GAS SORPTION AND TRANSPORT IN POLY (PHENYLENE OXIDE)(PPO)AND ARYL-BROMINATED PPO MEMBRANES[J]. 1989, 7(4): 306-314.
[1]贾连达,F. R. SHEU,R.T.CHERN,H.B.HOPFENBERG.GAS SORPTION AND TRANSPORT IN POLY (PHENYLENE OXIDE)(PPO)AND ARYL-BROMINATED PPO MEMBRANES[J].Chinese Journal of Polymer Science,1989,{4}(04):306-314. DOI：

JIA Lianda, F. R. SHEU, R.T.CHERN, et al. GAS SORPTION AND TRANSPORT IN POLY (PHENYLENE OXIDE)(PPO)AND ARYL-BROMINATED PPO MEMBRANES[J]. 1989, 7(4): 306-314. DOI：

摘要

正

The apparent solubility （S）

concentration-average diffusivity （D）

and permeability （P）

for C0

and N

through PPO and aryl-brominated PPO at 35℃for pressure ranging from 1 to 26 atm are reported. It is found that P

and S of the membranes to all the three gases vary with the extent of bromination. S increases with the increase of the percent of bromine in each case

but D to CO

increases remarkably only at higher degree of brominafion

and therefore

P to CO

is increased by more than 100% over a wide range ofpressure in the case. The solubility data are well described by the dual mode sorption model. It is found that the gas molecules sorbed by the Langmuir mode are relatively more immobilized and the contribution of the nonequilibrinm character of the polymer to gas permeation increases obviously for CO

and is hardly changed for CH

with increasing bromine content. These observations are interpreted in terms of changes in specific free volume （SFV）and the cohesive energy density （CED） of the polymers.

Abstract

The apparent solubility （S）

concentration-average diffusivity （D）

and permeability （P）

for C0

and N

through PPO and aryl-brominated PPO at 35℃ for pressure ranging from 1 to 26 atm are reported. It is found that P

and S of the membranes to all the three gases vary with the extent of bromination. S increases with the increase of the percent of bromine in each case

but D to CO

increases remarkably only at higher degree of brominafion

and therefore

P to CO

and is hardly changed for CH

with increasing bromine content. These observations are interpreted in terms of changes in specific free volume （SFV）and the cohesive energy density （CED） of the polymers.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Alternating Poly(ether-alt-ester)s with High Glass Transition Temperature Enabled by Rotationally Constrained Biaryl Units

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers

Related Author

No data

Related Institution

No data

⁰