DETERMINATION OFTHE CRYSTALLINITY IN DIFFERENT TYPE POLY (OXYETHYLENE-STYRENE)BLOCK COPOLYMERS BY X-RAY DIFFRACTION METHOD
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DETERMINATION OFTHE CRYSTALLINITY IN DIFFERENT TYPE POLY (OXYETHYLENE-STYRENE)BLOCK COPOLYMERS BY X-RAY DIFFRACTION METHOD
Vol. 7, Issue 4, Pages: 315-321(1989)
Affiliations:
1. Hubei Research Institute of Chemistry,Wuhan
2. Wuhan
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Published:20 December 1989
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[1]姚宁.DETERMINATION OFTHE CRYSTALLINITY IN DIFFERENT TYPE POLY (OXYETHYLENE-STYRENE)BLOCK COPOLYMERS BY X-RAY DIFFRACTION METHOD[J].Chinese Journal of Polymer Science,1989,{4}(04):315-321.
YAO Ning. DETERMINATION OFTHE CRYSTALLINITY IN DIFFERENT TYPE POLY (OXYETHYLENE-STYRENE)BLOCK COPOLYMERS BY X-RAY DIFFRACTION METHOD[J]. 1989, 7(4): 315-321.
[1]姚宁.DETERMINATION OFTHE CRYSTALLINITY IN DIFFERENT TYPE POLY (OXYETHYLENE-STYRENE)BLOCK COPOLYMERS BY X-RAY DIFFRACTION METHOD[J].Chinese Journal of Polymer Science,1989,{4}(04):315-321.DOI:
YAO Ning. DETERMINATION OFTHE CRYSTALLINITY IN DIFFERENT TYPE POLY (OXYETHYLENE-STYRENE)BLOCK COPOLYMERS BY X-RAY DIFFRACTION METHOD[J]. 1989, 7(4): 315-321.DOI:
DETERMINATION OFTHE CRYSTALLINITY IN DIFFERENT TYPE POLY (OXYETHYLENE-STYRENE)BLOCK COPOLYMERS BY X-RAY DIFFRACTION METHOD
<正> By means of the intensity theory of X-ray scattering and the two-phase concept of high polymer
the basic formula of the crystaUinity in block copolymers has been proposed after the corrections of atomic
temperature
absorption
Lorentz and polarization factor. Application of this method to different type poly (oxyethylene-styrene)block copolymers and the same type block copolymers with different EO contents indicates that the crystallinity in poly (oxyethylene-styrene ) block copolymers increases with the increase of the EO content and decreases in the order: PEO-PS-PEO>PEO-PS>PS-PEO-PS.
Abstract
By means of the intensity theory of X-ray scattering and the two-phase concept of high polymer
the basic formula of the crystaUinity in block copolymers has been proposed after the corrections of atomic
temperature
absorption
Lorentz and polarization factor. Application of this method to different type poly (oxyethylene-styrene)block copolymers and the same type block copolymers with different EO contents indicates that the crystallinity in poly (oxyethylene-styrene ) block copolymers increases with the increase of the EO content and decreases in the order: PEO-PS-PEO>PEO-PS>PS-PEO-PS.
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