THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE*
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THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE*
Vol. 7, Issue 4, Pages: 340-345(1989)
Affiliations:
1. Guangzhou Institute of Chemistry, Academia Sinica,Guangzhou
2. Academia Sinica
Author bio:
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DOI:
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Published:20 December 1989
Accepted:
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[1]黄勇.THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE[J].Chinese Journal of Polymer Science,1989,{4}(04):340-345.
HUANG Yong. THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE*[J]. 1989, 7(4): 340-345.
[1]黄勇.THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE[J].Chinese Journal of Polymer Science,1989,{4}(04):340-345.DOI:
HUANG Yong. THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE*[J]. 1989, 7(4): 340-345.DOI:
THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE*
<正> Ethyl-cyanoethyl cellulose ((E-CE)C)/styrene solution could form anisotropic system when the concentration was high enough. The (E-CE)C/polystyrene(PS)multiphase polymer could be obtained by radical polymerization of the styrene in the solution. The (E-CE)C/PS multiphase polymer maintained both the crystalline structure of the (E-CE)C and the amorphous structure of the PS. In the multiphase polymer produced from the isotropic solution
however
the (E-CE)C formed spherulites and spread in the PS amorphous phase. While
in the multiphase polymer produced from the anisotropic solution
the (E-CE)formed cylinderic crystalline aggregates. Moreover
the ordered lamellar texture was also observed in the multiphase polymer produced from the anisotropic solution.
Abstract
Ethyl-cyanoethyl cellulose ((E-CE)C)/styrene solution could form anisotropic system when the concentration was high enough. The (E-CE)C/polystyrene(PS)multiphase polymer could be obtained by radical polymerization of the styrene in the solution. The (E-CE)C/PS multiphase polymer maintained both the crystalline structure of the (E-CE)C and the amorphous structure of the PS. In the multiphase polymer produced from the isotropic solution
however
the (E-CE)C formed spherulites and spread in the PS amorphous phase. While
in the multiphase polymer produced from the anisotropic solution
the (E-CE)formed cylinderic crystalline aggregates. Moreover
the ordered lamellar texture was also observed in the multiphase polymer produced from the anisotropic solution.
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