EFFECT OF SOLVENT ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAMETHYL 4-PIPERIDINYL METHACRYLATE WITH STYRENE

ZHAO Ruinian; LIANG Wenzhong

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EFFECT OF SOLVENT ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAMETHYL 4-PIPERIDINYL METHACRYLATE WITH STYRENE

Papers | Updated：2021-06-21

- EFFECT OF SOLVENT ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAMETHYL 4-PIPERIDINYL METHACRYLATE WITH STYRENE
- Vol. 6, Issue 3, Pages: 223-229(1988)
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- Published：20 September 1988
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ZHAO Ruinian, LIANG Wenzhong. EFFECT OF SOLVENT ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAMETHYL 4-PIPERIDINYL METHACRYLATE WITH STYRENE[J]. 1988, 6(3): 223-229.
DOI：

ZHAO Ruinian, LIANG Wenzhong. EFFECT OF SOLVENT ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAMETHYL 4-PIPERIDINYL METHACRYLATE WITH STYRENE[J]. 1988, 6(3): 223-229. DOI：

摘要

The radical copolymerizations of 2

6-tetramethyl 4-piperidinyl methacrylate (TMPM) with styrene in various solvents have been studied. The monomer reactivity ratios r1 and r2 were determined. It is observed that in all of these reaction systems

there are appreciable solvent effects on both r1 and r2

which can be correlated to the difference in chemical shifts of olefinic protons of TMPM. And the variance of the copolymer microstructure in various media was discussed.

Abstract

The radical copolymerizations of 2

there are appreciable solvent effects on both r1 and r2

which can be correlated to the difference in chemical shifts of olefinic protons of TMPM. And the variance of the copolymer microstructure in various media was discussed.

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