SPONTANEOUS COPOLYMERIZATION OF 4-METHYLENE-1,3-DIOXOLANE DERIVATIVES WITH ACRYLONITRILE AND SUBSTITUENT EFFECT

PAN Caiyuan; WU Zheng

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SPONTANEOUS COPOLYMERIZATION OF 4-METHYLENE-1,3-DIOXOLANE DERIVATIVES WITH ACRYLONITRILE AND SUBSTITUENT EFFECT

Papers | Updated：2021-06-21

- SPONTANEOUS COPOLYMERIZATION OF 4-METHYLENE-1,3-DIOXOLANE DERIVATIVES WITH ACRYLONITRILE AND SUBSTITUENT EFFECT
- Vol. 6, Issue 3, Pages: 266-273(1988)
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- Published：20 September 1988
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PAN Caiyuan, WU Zheng. SPONTANEOUS COPOLYMERIZATION OF 4-METHYLENE-1,3-DIOXOLANE DERIVATIVES WITH ACRYLONITRILE AND SUBSTITUENT EFFECT[J]. 1988, 6(3): 266-273.
DOI：

PAN Caiyuan, WU Zheng. SPONTANEOUS COPOLYMERIZATION OF 4-METHYLENE-1,3-DIOXOLANE DERIVATIVES WITH ACRYLONITRILE AND SUBSTITUENT EFFECT[J]. 1988, 6(3): 266-273. DOI：

摘要

The copolymerization of six 2-substituted 4-methylene-1

3-dioxolane with aerylonitrile(AN) gives rise spontaneously to the alternating copolymers by the participation of charge-transfer(CT) complexes. The structures of copolymers was ascertained by their IR

1H and 13C NMR spectra

etc.. The electron effect of suhstituents on 2-position of monomer 2 is the most important factor in predicting the reactivity of CT complexes. However the steric effect determines the ring-opening degree of monomer 2. The spontaneous copolymerization mechanism has been discussed.

Abstract

The copolymerization of six 2-substituted 4-methylene-1

1H and 13C NMR spectra

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