PHOTOPOLYMERIZATION IN THE MICELLAR SYSTEMSⅡ THE CATALYSIS OF PKT FUNCTIONAL MICELLE*

WANG Erjian; FANG Peiji

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PHOTOPOLYMERIZATION IN THE MICELLAR SYSTEMSⅡ THE CATALYSIS OF PKT FUNCTIONAL MICELLE*

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- PHOTOPOLYMERIZATION IN THE MICELLAR SYSTEMSⅡ THE CATALYSIS OF PKT FUNCTIONAL MICELLE*
- Vol. 6, Issue 4, Pages: 299-305(1988)
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- Published：20 December 1988
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WANG Erjian, FANG Peiji. PHOTOPOLYMERIZATION IN THE MICELLAR SYSTEMSⅡ THE CATALYSIS OF PKT FUNCTIONAL MICELLE*[J]. 1988, 6(4): 299-305.
DOI：

WANG Erjian, FANG Peiji. PHOTOPOLYMERIZATION IN THE MICELLAR SYSTEMSⅡ THE CATALYSIS OF PKT FUNCTIONAL MICELLE*[J]. 1988, 6(4): 299-305. DOI：

摘要

A kind of cationic compounds

having benzophenone end group and various length chain (PKT) (BP-CH2N+R2R'·X-

R&R' different chain iength alkyl group) were used as photosensitizers. Various BP/TEA systems have been used for study

The efficiency of MMA photopolymerization initiated by them shows PKT>BP in homogeneous water solution and PKT> BP/CTAB in micellar water solution. The results obtained indicate that catalytic effects of PKT type functional micelles are far greater than that of common micelle with the enhancement of polymerization rate over 10 tiomes compared with BP in water solution.The catalytic role

reaction character of PKT

effect of counter ions and retarding effect of oxygen have also been discussed.

Abstract

A kind of cationic compounds

having benzophenone end group and various length chain (PKT) (BP-CH2N+R2R'·X-

R&R' different chain iength alkyl group) were used as photosensitizers. Various BP/TEA systems have been used for study

reaction character of PKT

effect of counter ions and retarding effect of oxygen have also been discussed.

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