SYNTHESIS AND CHARACTERIZATION OF TITANOCENE POLYMER DERIVATIVES*

WANG Zhuting; SUN Shumen

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SYNTHESIS AND CHARACTERIZATION OF TITANOCENE POLYMER DERIVATIVES*

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- SYNTHESIS AND CHARACTERIZATION OF TITANOCENE POLYMER DERIVATIVES*
- Vol. 6, Issue 4, Pages: 359-364(1988)
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- Published：20 December 1988
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WANG Zhuting, SUN Shumen. SYNTHESIS AND CHARACTERIZATION OF TITANOCENE POLYMER DERIVATIVES*[J]. 1988, 6(4): 359-364.
DOI：

WANG Zhuting, SUN Shumen. SYNTHESIS AND CHARACTERIZATION OF TITANOCENE POLYMER DERIVATIVES*[J]. 1988, 6(4): 359-364. DOI：

摘要

Titanocene polymer derivatives with potential antitumor properties were synthesized by interfacial condensation. The preformed polymers used are PAA (polyacrylic acid)

CPSMA (1:1 alternating copolymer of styrene and maleic anhydride) and DVEMA (1:2 copolymer of divinyl ether and maleic anhydride). The ratio of practical and theoretical titanium content is 73.6%

92.2% and 86.2% for PAA

CPSMA and DVEMA polymer derivatives respectively. The IR spectra of the polymer derivatives possess the characteristic absorptions of titanocene.XPS(X-ray photoelectron spectroscopy) of O1s and Ti2p3/2 supports the existence of Ti-O bonding.

Abstract

Titanocene polymer derivatives with potential antitumor properties were synthesized by interfacial condensation. The preformed polymers used are PAA (polyacrylic acid)

CPSMA (1:1 alternating copolymer of styrene and maleic anhydride) and DVEMA (1:2 copolymer of divinyl ether and maleic anhydride). The ratio of practical and theoretical titanium content is 73.6%

92.2% and 86.2% for PAA

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