GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY(N-PARA-TOLYLACRYLAMIDE) FILMS INITIATED BY CERIC ION

QIU Kunyuan; SONG Ye

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GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY(N-PARA-TOLYLACRYLAMIDE) FILMS INITIATED BY CERIC ION

Papers | Updated：2021-06-21

- GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY(N-PARA-TOLYLACRYLAMIDE) FILMS INITIATED BY CERIC ION
- Vol. 6, Issue 1, Pages: 75-83(1988)
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- Published：20 March 1988
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QIU Kunyuan, SONG Ye. GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY(N-PARA-TOLYLACRYLAMIDE) FILMS INITIATED BY CERIC ION[J]. 1988, 6(1): 75-83.
DOI：

QIU Kunyuan, SONG Ye. GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY(N-PARA-TOLYLACRYLAMIDE) FILMS INITIATED BY CERIC ION[J]. 1988, 6(1): 75-83. DOI：

摘要

Functional monomers having phenylcarbamoyl and p-tolylcarbamoyl were synthesized. Binary initiation system consisted of Ce4+ and these functional monomers could initiate acrylamide polymerization. It was found that acrylamide could graft copolymerize onto macromolecules having these functional monomers units. The formation of graft copolymer has been verified by its percentage of water absorption

contact angle with water

XPS and SEM photographs. The reaction mechanism was proposed and the main reactive site of graft copolymerization by Ce4+ would take place predominantly at the functional pendant group.

Abstract

contact angle with water

XPS and SEM photographs. The reaction mechanism was proposed and the main reactive site of graft copolymerization by Ce4+ would take place predominantly at the functional pendant group.

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