INCORPORATION OF METAL IONS INTO POLYPHENYLQUINOXALINE*

ZHANG Chi; LU Fengcai

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INCORPORATION OF METAL IONS INTO POLYPHENYLQUINOXALINE*

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- INCORPORATION OF METAL IONS INTO POLYPHENYLQUINOXALINE*
- Vol. 5, Issue 1, Pages: 40-44(1987)
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- Published：20 March 1987
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ZHANG Chi, LU Fengcai. INCORPORATION OF METAL IONS INTO POLYPHENYLQUINOXALINE*[J]. 1987, 5(1): 40-44.
DOI：

ZHANG Chi, LU Fengcai. INCORPORATION OF METAL IONS INTO POLYPHENYLQUINOXALINE*[J]. 1987, 5(1): 40-44. DOI：

摘要

FeCl3·6H2O

NiCl2

CuCl2

ZnCl2 and CrCl3 have been incorporated into polyphenylquinoxaline by a new method. High-quality

flexible

glass-cast films have been obtained which exhibit increased glass transition temperature and excellent thermal stability. Moduli and tensile strengths of the metal-containing polyphenylquinoxaline films increase surprisingly at elevated temperature. Electrical resistivities of these films fall in the same order range as polyphenylquinoxaline alone. X-ray photoelectron spectroscopic study of metal-containing polyphenylquinoxaline films shows that all metals in these films are present in the ionic state

there is charge transfer between nitrogen of polyphentlquinoxaline and Cu2+

Zn2+ of CuCl2

ZnCl2 containing polyphentlquimoxaline films.

Abstract

FeCl3·6H2O

NiCl2

CuCl2

ZnCl2 and CrCl3 have been incorporated into polyphenylquinoxaline by a new method. High-quality

flexible

there is charge transfer between nitrogen of polyphentlquinoxaline and Cu2+

Zn2+ of CuCl2

ZnCl2 containing polyphentlquimoxaline films.

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