SYNTHESES AND STRUCTURES OF POLYPHENYLSILSESQUIOXANES

ZHANG Xinsheng; SHI Lianghe

Your Location：

Home >

Browse articles >

SYNTHESES AND STRUCTURES OF POLYPHENYLSILSESQUIOXANES

Papers | Updated：2021-06-21

- SYNTHESES AND STRUCTURES OF POLYPHENYLSILSESQUIOXANES
- Vol. 5, Issue 3, Pages: 197-204(1987)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 September 1987
- Accepted：
Scan QR Code
ZHANG Xinsheng, SHI Lianghe. SYNTHESES AND STRUCTURES OF POLYPHENYLSILSESQUIOXANES[J]. 1987, 5(3): 197-204.
DOI：

ZHANG Xinsheng, SHI Lianghe. SYNTHESES AND STRUCTURES OF POLYPHENYLSILSESQUIOXANES[J]. 1987, 5(3): 197-204. DOI：

摘要

Phenyltrichlorosilane was hydrolyzed both ifi. toluene and in ether from which two kinds of prepolymers were obtained with different structures

molecular weights

and molecular weight distributions. Polymers were prepared from the prepolymers in various polymerization conditions. The ladderlike

branched

and crosslinked structures formed under different polymerization conditions were characterized by means of FTIR

1H and 29Si-NMR

and elemental analysis. Azeotropic distillation of solvents and H2O from the system and high molecular weight products with perfect ladderlike structure were obtained.

Abstract

Phenyltrichlorosilane was hydrolyzed both ifi. toluene and in ether from which two kinds of prepolymers were obtained with different structures

molecular weights

and molecular weight distributions. Polymers were prepared from the prepolymers in various polymerization conditions. The ladderlike

branched

and crosslinked structures formed under different polymerization conditions were characterized by means of FTIR

1H and 29Si-NMR

and elemental analysis. Azeotropic distillation of solvents and H2O from the system and high molecular weight products with perfect ladderlike structure were obtained.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Enhancing Processability of Phenylethynyl-terminated Imide Oligomers and Properties of Cured Polyimides via ―CF3 Incorporation

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

Related Author

No data

Related Institution

No data

⁰