ORGANOSILANE POLYMERS: SYNTHESIS AND CROSSLINKING OF FORMABLE POLYMERS CONTAINING PHENYLSILYLENE UNITS

ZHANG Xinghua; Robert West

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ORGANOSILANE POLYMERS: SYNTHESIS AND CROSSLINKING OF FORMABLE POLYMERS CONTAINING PHENYLSILYLENE UNITS

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- ORGANOSILANE POLYMERS: SYNTHESIS AND CROSSLINKING OF FORMABLE POLYMERS CONTAINING PHENYLSILYLENE UNITS
- Vol. 5, Issue 3, Pages: 240-253(1987)
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- Published：20 September 1987
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ZHANG Xinghua, Robert West. ORGANOSILANE POLYMERS: SYNTHESIS AND CROSSLINKING OF FORMABLE POLYMERS CONTAINING PHENYLSILYLENE UNITS[J]. 1987, 5(3): 240-253.
DOI：

ZHANG Xinghua, Robert West. ORGANOSILANE POLYMERS: SYNTHESIS AND CROSSLINKING OF FORMABLE POLYMERS CONTAINING PHENYLSILYLENE UNITS[J]. 1987, 5(3): 240-253. DOI：

摘要

Polysilane polymers which contain silicon hydride units in the chain were synthesized by sodium coupling of PhHSiCl2 with R1R2SiCl2 in toluene (R1 and R2 alkyl

aryl or aralkyl)

followed by termination with a monochlorosilane and neutralization with sodium bicarbonate solution. These polymers are soluble in common solvents and can be formed into a variety of shapes by molding

casting

coating or potting. This class of polymers can be crosslinked by oxidation and irradiation

or by reaction with a multifunctional vinylsilane in th presence of platinum complexes.

Abstract

Polysilane polymers which contain silicon hydride units in the chain were synthesized by sodium coupling of PhHSiCl2 with R1R2SiCl2 in toluene (R1 and R2 alkyl

aryl or aralkyl)

casting

coating or potting. This class of polymers can be crosslinked by oxidation and irradiation

or by reaction with a multifunctional vinylsilane in th presence of platinum complexes.

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