A series of polyurethane based on liquid chloroprene-hydroxyethyl methacrylate copolymer(CP-co-HEMA)-polystyrene (PS) interpenetrating polymer networks (PU-PS IPN) were synthe-sized. Some physical properties were examined and density behavior was investigated. In 60% polyurethane (PU) system
the tensile strength and density increased greatly. Transmission electronmicrographs showed that the phase separation existed and the sizes of PS domains dispersed in PUphase were about 500-4
000 A. In comparison with correlative PU-PMMA IPN system
which has the higher compatibility
this system showed an extensive phase separation and clear boundaries.There was no phase inversion observed even for 60% PU system in which PS was still the dispersed phase and PU the continuous phase.This was due to the relatively faster rate of formation of PU than that of ST polymerization.
Abstract
A series of polyurethane based on liquid chloroprene-hydroxyethyl methacrylate copolymer(CP-co-HEMA)-polystyrene (PS) interpenetrating polymer networks (PU-PS IPN) were synthe-sized. Some physical properties were examined and density behavior was investigated. In 60% polyurethane (PU) system
the tensile strength and density increased greatly. Transmission electronmicrographs showed that the phase separation existed and the sizes of PS domains dispersed in PUphase were about 500-4
000 A. In comparison with correlative PU-PMMA IPN system
which has the higher compatibility
this system showed an extensive phase separation and clear boundaries.There was no phase inversion observed even for 60% PU system in which PS was still the dispersed phase and PU the continuous phase.This was due to the relatively faster rate of formation of PU than that of ST polymerization.
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