bromohydroquinone or dihydroxybi-phenyl) was prepared. 1H-NMR studies revealed that the monomer units had microstructures closeto random distribution in the chains. The copolymers showed composition-dependent liquid crystal-line properties as verified by visual observation of stir opalescence
polarizing microscope
DSC andX-ray diffration. The copolyesters with aromatic diol contents over a certain extent(for chloro-hydroquinone m≥0.33) were thermotropic with wide liquid crystalline temperature ranges.The introduction of chlorohydroquinone into the copolyesters could gradually destroy the crystallinity of the polymers but retain the liquid crystalline characteristics.
Abstract
A series of copolyesters based on bis(4-hydroxybutyl) terephthalate
bromohydroquinone or dihydroxybi-phenyl) was prepared. 1H-NMR studies revealed that the monomer units had microstructures closeto random distribution in the chains. The copolymers showed composition-dependent liquid crystal-line properties as verified by visual observation of stir opalescence
polarizing microscope
DSC andX-ray diffration. The copolyesters with aromatic diol contents over a certain extent(for chloro-hydroquinone m≥0.33) were thermotropic with wide liquid crystalline temperature ranges.The introduction of chlorohydroquinone into the copolyesters could gradually destroy the crystallinity of the polymers but retain the liquid crystalline characteristics.
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