STRUCTURE OF PLASMA-POLYMERIZED OCTAFLUOROCYCLOBUTANE

YE Mu; CHEN Jie; LU Lizhen; HU Huizhen; XIAO Yanwen; LIU Guizhen

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STRUCTURE OF PLASMA-POLYMERIZED OCTAFLUOROCYCLOBUTANE

Papers | Updated：2021-06-21

- STRUCTURE OF PLASMA-POLYMERIZED OCTAFLUOROCYCLOBUTANE
- Vol. 4, Issue 3, Pages: 256-261(1986)
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- Published：20 September 1986
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YE Mu, CHEN Jie, LU Lizhen, et al. STRUCTURE OF PLASMA-POLYMERIZED OCTAFLUOROCYCLOBUTANE[J]. 1986, 4(3): 256-261.
DOI：

YE Mu, CHEN Jie, LU Lizhen, et al. STRUCTURE OF PLASMA-POLYMERIZED OCTAFLUOROCYCLOBUTANE[J]. 1986, 4(3): 256-261. DOI：

摘要

Plasma-polymerization of octafluorocyclobutane was carried out in a capacitively coupled tubu-lar reactor with external electrodes. The number-average molecular weight

melting temperature

decomposition temperature and solubility in te trafluorodibromoethane of the products was mea-sured and the polymer structure was characterized by ESR. IR and19F-NMR methods. The experi-mental results show the absence of the highly crosslinked structure but a fluorine-deficient structurecaused by free-radicals

carbonyl groups

double bonds and multicage-like segments in the polymer.

Abstract

Plasma-polymerization of octafluorocyclobutane was carried out in a capacitively coupled tubu-lar reactor with external electrodes. The number-average molecular weight

melting temperature

carbonyl groups

double bonds and multicage-like segments in the polymer.

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