THE EFFECT OF MODIFICATION OF COORDINATING GROUPS ON THE CATALYTIC BEHAVIORS OF POLYMER CATALYSTS

BAI Ruke; ZONG Huijuan; XU; Dawei; HE Jigang

Your Location：

Home >

Browse articles >

THE EFFECT OF MODIFICATION OF COORDINATING GROUPS ON THE CATALYTIC BEHAVIORS OF POLYMER CATALYSTS

Papers | Updated：2021-06-21

- THE EFFECT OF MODIFICATION OF COORDINATING GROUPS ON THE CATALYTIC BEHAVIORS OF POLYMER CATALYSTS
- Vol. 4, Issue 1, Pages: 65-71(1986)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 March 1986
- Accepted：
Scan QR Code
BAI Ruke, ZONG Huijuan, XU, et al. THE EFFECT OF MODIFICATION OF COORDINATING GROUPS ON THE CATALYTIC BEHAVIORS OF POLYMER CATALYSTS[J]. 1986, 4(1): 65-71.
DOI：

BAI Ruke, ZONG Huijuan, XU, et al. THE EFFECT OF MODIFICATION OF COORDINATING GROUPS ON THE CATALYTIC BEHAVIORS OF POLYMER CATALYSTS[J]. 1986, 4(1): 65-71. DOI：

摘要

Several polymer-supported palladium complex catalysts containing two different coordinating groups were prepared and the cooperative effect of the coordinating groups on the catalytic behaviors of polymer catalysts was studied. It was found that poly(acrylic acid-co-acrylonitrile)-Pd complex(PAA-AN-Pd) is a more active and stable catalyst for hydrogenation than both poly(acrylic acid)-Pd and poly(acrylonitrile)-Pd complexes. A marked change of catalytic behaviors of poly(N-substituted maleamic acid-co-styrene)-Pd complexes was observed in comparison with poly(maleic acid-co-styrene)-Pd complex.Acetophenone was reduced to 1-phenyl ethanol by poly(N-phenyl maleamic acid-co-styrene)-Pd complex (N-1-Pd)

but ethylbenzene was obtained using poly(maleic acid-co-styrene)-Pd complex as a catalyst.The influence of solvents

additives and N/Pd gram atomic ratio on the catalttic behaviors of the polymer complexes was investigated.

Abstract

but ethylbenzene was obtained using poly(maleic acid-co-styrene)-Pd complex as a catalyst.The influence of solvents

additives and N/Pd gram atomic ratio on the catalttic behaviors of the polymer complexes was investigated.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Enhancing Processability of Phenylethynyl-terminated Imide Oligomers and Properties of Cured Polyimides via ―CF3 Incorporation

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

Sequence-encoded Conformation Pathways in Viscoelastic Microphase Separation of Multiblock Copolymers

Related Author

No data

Related Institution

No data

⁰